Exceptional activity for direct synthesis of phenol from benzene over PMoV@MOF with O-2
文献类型：期刊论文
| 作者 | Yang, Hua1,2; Li, Jun1,2; Wang, Lianyue1,2; Dai, Wen1,2,3; Lv, Ying1,2; Gao, Shuang1,2 |
| 刊名 | catalysis communications
 |
| 出版日期 | 2013-05-05 |
| 卷号 | 35页码:101-104 |
| 关键词 | Polyoxometalates MOFs Oxygen Benzene Phenol |
| 英文摘要 | three novel catalysts named as pmo12-nvn@hkust-1 (n=1-3) were designed and obtained through encapsulating vanadium-doped keggin polyoxometalates (poms) pmo12-n v-n into the framework hkust-1 (also denoted as cu-3(btc)(2), mof-199). the character structure of pmo12-n v-n@hkust-1 was elucidated through the single crystal xrd of pmo11v@hkust-1. reaction rate could be greatly enhanced by pmo12-n v-n@hkust-1 in liquid hydroxylation of benzene with o-2. only in 20 min, a high tof (442 h(-1)) of pmo9v3@hkust-1 was obtained. (c) 2013 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | metal-organic framework ; selective hydroxylation ; mesoporous silica ; oxidation ; catalysts ; oxide ; reactivity ; stability ; dioxygen ; hydrogen |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000317883100020 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137675]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Hua,Li, Jun,Wang, Lianyue,et al. Exceptional activity for direct synthesis of phenol from benzene over PMoV@MOF with O-2[J]. catalysis communications,2013,35:101-104. |
| APA | Yang, Hua,Li, Jun,Wang, Lianyue,Dai, Wen,Lv, Ying,&Gao, Shuang.(2013).Exceptional activity for direct synthesis of phenol from benzene over PMoV@MOF with O-2.catalysis communications,35,101-104. |
| MLA | Yang, Hua,et al."Exceptional activity for direct synthesis of phenol from benzene over PMoV@MOF with O-2".catalysis communications 35(2013):101-104. |
入库方式： OAI收割
来源：大连化学物理研究所
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