Conversion of furfural into cyclopentanone over Ni-Cu bimetallic catalysts
文献类型：期刊论文
| 作者 | Yang, Yanliang1,2; Du, Zhongtian1; Huang, Yizheng1; Lu, Fang1; Wang, Feng1; Gao, Jin1; Xu, Jie1 |
| 刊名 | green chemistry
 |
| 出版日期 | 2013 |
| 卷号 | 15期号:7页码:1932-1940 |
| 英文摘要 | the conversion of furfural into cyclopentanone over ni-cu bimetallic catalysts was studied under hydrogen atmosphere. furfuryl alcohol, 4-hydroxy-2-cyclopentenone and 2-cyclopentenone were verified as three key intermediates. rearrangement of the furan ring was independent of hydrogenation, starting from furfuryl alcohol rather than furfural. the opening and closure of the furan ring were closely related to the attack of a h2o molecule on the 5-position of furfuryl alcohol. prior hydrogenation of the aldehyde group accounted for the different reactivity of furfural and furfuryl alcohol. the high selectivity of cyclopentanone was ascribed to the presence of 2-cyclopentenone. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | vapor-phase hydrogenation ; acidic ionic liquids ; biomass ; chemicals ; efficient ; sugars ; hydrogenolysis ; transformation ; hydrocarbons ; dehydration |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000320781200021 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137677]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Yanliang,Du, Zhongtian,Huang, Yizheng,et al. Conversion of furfural into cyclopentanone over Ni-Cu bimetallic catalysts[J]. green chemistry,2013,15(7):1932-1940. |
| APA | Yang, Yanliang.,Du, Zhongtian.,Huang, Yizheng.,Lu, Fang.,Wang, Feng.,...&Xu, Jie.(2013).Conversion of furfural into cyclopentanone over Ni-Cu bimetallic catalysts.green chemistry,15(7),1932-1940. |
| MLA | Yang, Yanliang,et al."Conversion of furfural into cyclopentanone over Ni-Cu bimetallic catalysts".green chemistry 15.7(2013):1932-1940. |
入库方式： OAI收割
来源：大连化学物理研究所
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