Correlation of Hydrogen Cyanide Formation with 2,5-Diketopiperazine and Nitrogen Heterocyclic Compounds from Co-pyrolysis of Glycine and Glucose/Fructose
文献类型：期刊论文
| 作者 | Hao, Jufang1,2; Guo, Jizhao2; Xie, Fuwei2; Xia, Qiaoling2; Xie, Jianping2 |
| 刊名 | energy & fuels
 |
| 出版日期 | 2013-08-01 |
| 卷号 | 27期号:8页码:4723-4728 |
| 英文摘要 | it is important to understand the formation of hydrogen cyanide (hcn) for minimizing the emissions of nox during biomass combustion. in the present study, glycine was used as the model compound of biomass n. the influences of reducing sugars (glucose and fructose) on the formation of hcn from glycine pyrolysis were investigated by analyzing the yields of hcn, 2,5-diketopiperazine (dkp), and n-heterocyclic compounds. the results indicated that the hcn yield from glycine pyrolysis decreased and the nitrogen distribution changed in the presence of glucose/fructose. of the thermal reactions, glycine might be more likely to react with reducing sugars to form a large number of n-heterocyclic compounds rather than polymerize to form dkp. the decrease of the hcn yield from co-pyrolysis of glycine and reducing sugars is related to the reduction of dkp and the increase of n-heterocyclic compounds. furthermore, analysis of label incorporation into hcn formation at different molar ratios of glycine/reducing sugar indicated that the contribution of reducing sugar to hcn formation might be more considerable with the increasing content of reducing sugar. |
| WOS标题词 | science & technology ; technology |
| 类目[WOS] | energy & fuels ; engineering, chemical |
| 研究领域[WOS] | energy & fuels ; engineering |
| 关键词[WOS] | model systems ; amino-acids ; maillard reaction ; n2o precursors ; fuel-n ; biomass ; combustion ; ph ; carbohydrate ; gasification |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000323301300065 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137692]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.CNTC, Zhengzhou Tobacco Res Inst, Zhengzhou 450001, Henan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hao, Jufang,Guo, Jizhao,Xie, Fuwei,et al. Correlation of Hydrogen Cyanide Formation with 2,5-Diketopiperazine and Nitrogen Heterocyclic Compounds from Co-pyrolysis of Glycine and Glucose/Fructose[J]. energy & fuels,2013,27(8):4723-4728. |
| APA | Hao, Jufang,Guo, Jizhao,Xie, Fuwei,Xia, Qiaoling,&Xie, Jianping.(2013).Correlation of Hydrogen Cyanide Formation with 2,5-Diketopiperazine and Nitrogen Heterocyclic Compounds from Co-pyrolysis of Glycine and Glucose/Fructose.energy & fuels,27(8),4723-4728. |
| MLA | Hao, Jufang,et al."Correlation of Hydrogen Cyanide Formation with 2,5-Diketopiperazine and Nitrogen Heterocyclic Compounds from Co-pyrolysis of Glycine and Glucose/Fructose".energy & fuels 27.8(2013):4723-4728. |
入库方式： OAI收割
来源：大连化学物理研究所
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