Heat capacities and thermodynamic properties of [Co(AIP)(BPY)(0.5)center dot H2O](n)center dot 2nH(2)O
文献类型：期刊论文
| 作者 | Li, Jiajie1,2; Xu, Fen2; Si, Xiaoliang2; Sun, Lixian2,3; Jiao, Qingzhu1; Jiao, Chengli2; Gu, Zhizhi1,2; Xin, He1,2 |
| 刊名 | thermochimica acta
 |
| 出版日期 | 2013-08-20 |
| 卷号 | 566页码:15-18 |
| 关键词 | [Co(AIP)(BPY)(0.5)center dot H2O](n)center dot 2nH(2)O Coordination polymer TMDSC Molar heat capacity TG |
| 英文摘要 | one three-dimensional coordination polymer [co(aip)(bpy)(0.5)center dot h2o](n)center dot 2nh(2)o (aip, 5-aminoisophthalic; bpy, 4,4'-bipyridine) has been synthesized solvothermally and characterized by powder x-ray diffraction, ft-ir spectra. the molar heat capacities of [co(aip)(bpy)(0.5)center dot h2o](n)center dot 2nh(2)o were measured by temperature modulated differential scanning calorimetry (tmdsc) over the temperature range of 188-3001k for the first time, and no phase transition or thermal anomaly was detected in the experimental temperature range. the thermodynamic parameters relative to the standard reference temperature 298.15k were derived based on the above molar heat capacities data. besides, a two-step sequential thermal decomposition mechanism for the material was investigated through the thermogravimetry (tg-dtg) from 300 to 1073 k. (c) 2013 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | metal-organic frameworks ; coordination polymers ; modulated dsc ; temperature ; storage ; water |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000322685700003 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137703]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China 2.Guilin Univ Elect Technol, Sch Mat Sci & Engn, Guilin 541004, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Jiajie,Xu, Fen,Si, Xiaoliang,et al. Heat capacities and thermodynamic properties of [Co(AIP)(BPY)(0.5)center dot H2O](n)center dot 2nH(2)O[J]. thermochimica acta,2013,566:15-18. |
| APA | Li, Jiajie.,Xu, Fen.,Si, Xiaoliang.,Sun, Lixian.,Jiao, Qingzhu.,...&Xin, He.(2013).Heat capacities and thermodynamic properties of [Co(AIP)(BPY)(0.5)center dot H2O](n)center dot 2nH(2)O.thermochimica acta,566,15-18. |
| MLA | Li, Jiajie,et al."Heat capacities and thermodynamic properties of [Co(AIP)(BPY)(0.5)center dot H2O](n)center dot 2nH(2)O".thermochimica acta 566(2013):15-18. |
入库方式： OAI收割
来源：大连化学物理研究所
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