中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Catalytic applications of OSDA-free Beta zeolite

文献类型:期刊论文

作者De Baerdemaeker, Trees1; Yilmaz, Bilge2; Mueller, Ulrich3; Feyen, Mathias3; Xiao, Feng-Shou4; Zhang, Weiping5; Tatsumi, Takashi6; Gies, Hermann7; Bao, Xinhe8; De Vos, Dirk1
刊名journal of catalysis
出版日期2013-12-01
卷号308页码:73-81
关键词Beta zeolite USDA-free synthesis Dealumination Alkylation Acylation Hydroconversion
英文摘要beta zeolite obtained from seeded synthesis without the use of organic structure directing agents (osdas) has been used as a catalyst in different types of reactions. the large number of strong acid sites resulted in a high activity for the alkylation of benzene with ethene and a high cracking activity in the hydroconversion of n-decane. however, the high framework polarity resulted in fast deactivation in the acylation of aromatic ethers. dealumination treatments resulted in improved stability in alkylation reactions with the more reactive olefins like propene. in acylation reactions, the activity was significantly increased, and in hydroconversion, a better balance between the hydrogenation/dehydrogenation and the acid sites was obtained. (c) 2013 elsevier inc. all rights reserved.
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, physical ; engineering, chemical
研究领域[WOS]chemistry ; engineering
关键词[WOS]liquid-phase alkylation ; linear alkylbenzene synthesis ; structure-directing agent ; fine chemicals synthesis ; seed-assisted synthesis ; mtw-type zeolite ; aluminosilicate gels ; selective oxidation ; organotemplate-free ; solid solvents
收录类别SCI
语种英语
WOS记录号WOS:000329881700008
公开日期2015-11-10
源URL[http://159.226.238.44/handle/321008/137707]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Heverlee, Belgium
2.BASF Corp, Chem Res & Engn, Iselin, NJ 08830 USA
3.BASF SE, Chem Res & Engn, D-67056 Ludwigshafen, Germany
4.Zhejiang Univ, Hangzhou 310028, Zhejiang, Peoples R China
5.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
6.Tokyo Inst Technol, Chem Resources Lab, Yokohama, Kanagawa 2268503, Japan
7.Ruhr Univ Bochum, Inst Geol Mineral & Geophys, D-44780 Bochum, Germany
8.Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
De Baerdemaeker, Trees,Yilmaz, Bilge,Mueller, Ulrich,et al. Catalytic applications of OSDA-free Beta zeolite[J]. journal of catalysis,2013,308:73-81.
APA De Baerdemaeker, Trees.,Yilmaz, Bilge.,Mueller, Ulrich.,Feyen, Mathias.,Xiao, Feng-Shou.,...&De Vos, Dirk.(2013).Catalytic applications of OSDA-free Beta zeolite.journal of catalysis,308,73-81.
MLA De Baerdemaeker, Trees,et al."Catalytic applications of OSDA-free Beta zeolite".journal of catalysis 308(2013):73-81.

入库方式: OAI收割

来源:大连化学物理研究所

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