High density Si/ZnO core/shell nanowire arrays for photoelectrochemical water splitting
文献类型:期刊论文
作者 | Ji, Jiuyu1; Zhang, Wenhua2; Zhang, Heqiu1; Qiu, Yu1; Wang, Yan3; Luo, Yingmin1; Hu, Lizhong1 |
刊名 | journal of materials science-materials in electronics
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出版日期 | 2013-09-01 |
卷号 | 24期号:9页码:3474-3480 |
英文摘要 | si/zno core/shell nanowire (nw) arrays were fabricated using atomic layer deposition of zno shell on n-si nw arrays prepared by metal assisted electroless etching method. scanning electron microscopy, transmission electron microscopy and x-ray diffraction were utilized to characterize the core/shell structures. water splitting performance of the core/shell structures was preliminarily studied. the si/zno core/shell nw arrays yielded significantly higher photocurrent density than the planar si/zno structure due to their low reflectance and high surface area. the photoelectrochemical efficiency was found to be 0.035 and 0.002 % for 10 mu m-long si/zno nw array and planar si/zno sample, respectively. these results suggested that core/shell structure is superior to planar heterojunction for pec electrode design. we demonstrated the dependence of photocurrent density on the length of the core/shell array, and analyzed the reasons why longer nw arrays could produce higher photocurrent density. the relationship between the thickness of zno shell and the photoconversion efficiency of si/zno nw arrays was also discussed. by applying the core/shell structure in electrode design, one may be able to improve the photoelectrochemical efficiency and photovoltaic device performance. |
WOS标题词 | science & technology ; technology ; physical sciences |
类目[WOS] | engineering, electrical & electronic ; materials science, multidisciplinary ; physics, applied ; physics, condensed matter |
研究领域[WOS] | engineering ; materials science ; physics |
关键词[WOS] | visible-light ; photovoltaic applications ; titanium-dioxide ; silicon ; photocatalyst ; absorption ; zno ; fabrication ; electrode ; surface |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000323249800049 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/137713] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Dalian Univ Technol, Sch Phys & Optoelect Technol, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Liaoning Normal Univ, Sch Phys & Elect Technol, Dalian 116029, Peoples R China |
推荐引用方式 GB/T 7714 | Ji, Jiuyu,Zhang, Wenhua,Zhang, Heqiu,et al. High density Si/ZnO core/shell nanowire arrays for photoelectrochemical water splitting[J]. journal of materials science-materials in electronics,2013,24(9):3474-3480. |
APA | Ji, Jiuyu.,Zhang, Wenhua.,Zhang, Heqiu.,Qiu, Yu.,Wang, Yan.,...&Hu, Lizhong.(2013).High density Si/ZnO core/shell nanowire arrays for photoelectrochemical water splitting.journal of materials science-materials in electronics,24(9),3474-3480. |
MLA | Ji, Jiuyu,et al."High density Si/ZnO core/shell nanowire arrays for photoelectrochemical water splitting".journal of materials science-materials in electronics 24.9(2013):3474-3480. |
入库方式: OAI收割
来源:大连化学物理研究所
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