The roles of hydroxyapatite and FeOx in a Au/FeOx-hydroxyapatite catalyst for CO oxidation
文献类型:期刊论文
作者 | Zhao Kunfeng1,2; Qiao Botao1; Zhang Yanjie1; Wang Junhu1 |
刊名 | chinese journal of catalysis
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出版日期 | 2013-07-01 |
卷号 | 34期号:7页码:1386-1394 |
关键词 | Gold Iron oxide Hydroxyapatite Carbon monoxide Sintering resistance |
英文摘要 | a feox modified hydroxyapatite (hap, ca-10(po4)(6)(oh)(2))-supported gold catalyst is highly active and stable during co oxidation at low temperature, and it is also sinter-resistant to calcination at temperature up to 600 degrees c. this work used catalyst characterization and activity tests to investigate the roles of the hap support and feox promoter in co oxidation. xps results suggested that a strong interaction between the hap support and the au and feox nanoparticles gave the sintering resistance. in situ drift studies revealed that the addition of feox changed the nature of the reaction mechanism and intermediates to promote catalytic activity. tem and mossbauer examination of the spent catalysts in combination with the in situ drift results suggested that the better stability of au/feox-hap originated from its better prevention of carbonate accumulation. (c) 2013, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
研究领域[WOS] | chemistry ; engineering |
关键词[WOS] | supported gold catalysts ; selective oxidation ; carbon-monoxide ; temperature ; performance ; fe2o3 ; phosphates ; adsorption ; mechanism ; al2o3 |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000322425500014 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/137717] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao Kunfeng,Qiao Botao,Zhang Yanjie,et al. The roles of hydroxyapatite and FeOx in a Au/FeOx-hydroxyapatite catalyst for CO oxidation[J]. chinese journal of catalysis,2013,34(7):1386-1394. |
APA | Zhao Kunfeng,Qiao Botao,Zhang Yanjie,&Wang Junhu.(2013).The roles of hydroxyapatite and FeOx in a Au/FeOx-hydroxyapatite catalyst for CO oxidation.chinese journal of catalysis,34(7),1386-1394. |
MLA | Zhao Kunfeng,et al."The roles of hydroxyapatite and FeOx in a Au/FeOx-hydroxyapatite catalyst for CO oxidation".chinese journal of catalysis 34.7(2013):1386-1394. |
入库方式: OAI收割
来源:大连化学物理研究所
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