中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Hydrolysis of hemicellulose catalyzed by hierarchical H-USY zeolites - The role of acidity and pore structure

文献类型:期刊论文

作者Zhou, Lipeng1; Shi, Meiting1; Cai, Qiyong1; Wu, Lin1; Hu, Xiaopeng1; Yang, Xiaomei1; Chen, Chen2; Xu, Jie2
刊名microporous and mesoporous materials
出版日期2013-03-15
卷号169页码:54-59
关键词Hierarchical zeolites Hemicellulose Hydrolysis Biomass
英文摘要hierarchical h-usy zeolite prepared by oxalic acid treatment was demonstrated to be an effective catalyst for the hydrolysis of hemicellulose. the yield of total reducing sugars (trs) increased remarkably to 55.7% over hierarchical h-usy compared with 5.8% yield of trs over h-usy-parent under the same reaction conditions. mesopores/macropores created by oxalic acid treatment played a main role in elevation of the yield of trs, which not only improved the accessibility of the acid sites, but also facilitated the product to diffuse out the catalyst and thus restrained its further conversion to byproducts. conditions of oxalic acid treatment for preparation of hierarchical h-usy zeolite and hydrolysis of hemicellulose were optimized to obtain high yield of trs. furthermore, hierarchical h-usy zeolite showed good activity in the selective hydrolysis of hemicellulose in lignocellulosic biomass. (c) 2012 elsevier inc. all rights reserved.
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary
研究领域[WOS]chemistry ; science & technology - other topics ; materials science
关键词[WOS]molecular-sieves ; ionic liquid ; solid acids ; cellulose ; dealumination ; oligosaccharides ; saccharides ; mesopores ; transport ; glucose
收录类别SCI
语种英语
WOS记录号WOS:000314384800008
公开日期2015-11-10
源URL[http://159.226.238.44/handle/321008/137761]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Zhou, Lipeng,Shi, Meiting,Cai, Qiyong,et al. Hydrolysis of hemicellulose catalyzed by hierarchical H-USY zeolites - The role of acidity and pore structure[J]. microporous and mesoporous materials,2013,169:54-59.
APA Zhou, Lipeng.,Shi, Meiting.,Cai, Qiyong.,Wu, Lin.,Hu, Xiaopeng.,...&Xu, Jie.(2013).Hydrolysis of hemicellulose catalyzed by hierarchical H-USY zeolites - The role of acidity and pore structure.microporous and mesoporous materials,169,54-59.
MLA Zhou, Lipeng,et al."Hydrolysis of hemicellulose catalyzed by hierarchical H-USY zeolites - The role of acidity and pore structure".microporous and mesoporous materials 169(2013):54-59.

入库方式: OAI收割

来源:大连化学物理研究所

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