Progress on the Catalytic Asymmetric Hydrogenation of Imines
文献类型:期刊论文
作者 | Wang Dong1; Hou Chuanjin1,2; Chen Lifeng1; Liu Xiaoning1; An Qingda1; Hu Xiangping2 |
刊名 | chinese journal of organic chemistry
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出版日期 | 2013-07-01 |
卷号 | 33期号:7页码:1355-1368 |
关键词 | imines asymmetric catalysis hydrogenation chiral ligand |
英文摘要 | chiral amines are important synthetic intermediates in the preparation of many physiologically active compounds. catalytic asymmetric hydrogenation of prochiral imines represents one of the most direct and convenient route to chiral amines and their derivatives. during the past two decades, significant progress has been made in the asymmetric hydrogenation of imines. many highly enantioselective chiral catalysts have been disclosed, some new methods and strategies have been developed, and some challenging imines substrates have been efficiently hydrogenated in high enantioselectivities. despite these achievements, catalytic asymmetric hydrogenation of imines still have challenges of low reactivity, narrow substrate scope, harsh hydrogenation conditions and difficulty in catalyst reuse. therefore, development of new catalyst system with high reactivity and enantioselectivity as well as environmental friendship in the asymmetric hydrogenation of imines is of great interest. this review presents a brief overview on the progress in catalytic asymmetric hydrogenation of cyclic and acyclic imines. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, organic |
研究领域[WOS] | chemistry |
关键词[WOS] | n-aryl imines ; highly enantioselective hydrogenation ; supercritical carbon-dioxide ; phosphine-oxazoline ligands ; chiral titanocene catalyst ; ru-msdpen catalysts ; iridium complexes ; transition-metal ; cyclic imines ; heteroaromatic-compounds |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000323797100001 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/137778] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Dalian Polytech Univ, Sch Light Ind & Chem Engn, Dalian 116034, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Wang Dong,Hou Chuanjin,Chen Lifeng,et al. Progress on the Catalytic Asymmetric Hydrogenation of Imines[J]. chinese journal of organic chemistry,2013,33(7):1355-1368. |
APA | Wang Dong,Hou Chuanjin,Chen Lifeng,Liu Xiaoning,An Qingda,&Hu Xiangping.(2013).Progress on the Catalytic Asymmetric Hydrogenation of Imines.chinese journal of organic chemistry,33(7),1355-1368. |
MLA | Wang Dong,et al."Progress on the Catalytic Asymmetric Hydrogenation of Imines".chinese journal of organic chemistry 33.7(2013):1355-1368. |
入库方式: OAI收割
来源:大连化学物理研究所
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