中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Progress on the Catalytic Asymmetric Hydrogenation of Imines

文献类型:期刊论文

作者Wang Dong1; Hou Chuanjin1,2; Chen Lifeng1; Liu Xiaoning1; An Qingda1; Hu Xiangping2
刊名chinese journal of organic chemistry
出版日期2013-07-01
卷号33期号:7页码:1355-1368
关键词imines asymmetric catalysis hydrogenation chiral ligand
英文摘要chiral amines are important synthetic intermediates in the preparation of many physiologically active compounds. catalytic asymmetric hydrogenation of prochiral imines represents one of the most direct and convenient route to chiral amines and their derivatives. during the past two decades, significant progress has been made in the asymmetric hydrogenation of imines. many highly enantioselective chiral catalysts have been disclosed, some new methods and strategies have been developed, and some challenging imines substrates have been efficiently hydrogenated in high enantioselectivities. despite these achievements, catalytic asymmetric hydrogenation of imines still have challenges of low reactivity, narrow substrate scope, harsh hydrogenation conditions and difficulty in catalyst reuse. therefore, development of new catalyst system with high reactivity and enantioselectivity as well as environmental friendship in the asymmetric hydrogenation of imines is of great interest. this review presents a brief overview on the progress in catalytic asymmetric hydrogenation of cyclic and acyclic imines.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, organic
研究领域[WOS]chemistry
关键词[WOS]n-aryl imines ; highly enantioselective hydrogenation ; supercritical carbon-dioxide ; phosphine-oxazoline ligands ; chiral titanocene catalyst ; ru-msdpen catalysts ; iridium complexes ; transition-metal ; cyclic imines ; heteroaromatic-compounds
收录类别SCI
语种英语
WOS记录号WOS:000323797100001
公开日期2015-11-10
源URL[http://159.226.238.44/handle/321008/137778]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Dalian Polytech Univ, Sch Light Ind & Chem Engn, Dalian 116034, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Wang Dong,Hou Chuanjin,Chen Lifeng,et al. Progress on the Catalytic Asymmetric Hydrogenation of Imines[J]. chinese journal of organic chemistry,2013,33(7):1355-1368.
APA Wang Dong,Hou Chuanjin,Chen Lifeng,Liu Xiaoning,An Qingda,&Hu Xiangping.(2013).Progress on the Catalytic Asymmetric Hydrogenation of Imines.chinese journal of organic chemistry,33(7),1355-1368.
MLA Wang Dong,et al."Progress on the Catalytic Asymmetric Hydrogenation of Imines".chinese journal of organic chemistry 33.7(2013):1355-1368.

入库方式: OAI收割

来源:大连化学物理研究所

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