An unexpected effect of water on the asymmetric hydrogenation of alpha-ketoesters on platinum nanoparticles confined in carbon nanotubes
文献类型：期刊论文
| 作者 | Guan, Zaihong; Lu, Shengmei; Chen, Zhijian; Li, Can |
| 刊名 | journal of catalysis
 |
| 出版日期 | 2013-09-01 |
| 卷号 | 305页码:19-26 |
| 关键词 | Carbon nanotubes Water effect Asymmetric hydrogenation |
| 英文摘要 | the influence of water on asymmetric hydrogenation of alpha-ketoesters on platinum nanoparticles confined in the channels of carbon nanotubes was investigated. as high as 95% enantioselectivity is achieved in the asymmetric hydrogenation of ethyl pyruvate in acetic acid/water solution compared with 86% enantioselectivity obtained in anhydrous acetic acid. the adsorption experiment confirmed that the presence of water can enrich the chiral modifier cinchonidine in the channels 3900 times of that in solution and also enhance the ability of the channels to discriminate between the reactant and product molecules with only small hydrophobic/hydrophilic difference that kinetically favors the catalytic reaction in the channels of carbon nanotubes. (c) 2013 published by elsevier inc. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | enantioselective hydrogenation ; ice nanotubes ; adsorption ; catalysis ; liquid ; iron ; nanofibers ; palladium |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000322501000003 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137782]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guan, Zaihong,Lu, Shengmei,Chen, Zhijian,et al. An unexpected effect of water on the asymmetric hydrogenation of alpha-ketoesters on platinum nanoparticles confined in carbon nanotubes[J]. journal of catalysis,2013,305:19-26. |
| APA | Guan, Zaihong,Lu, Shengmei,Chen, Zhijian,&Li, Can.(2013).An unexpected effect of water on the asymmetric hydrogenation of alpha-ketoesters on platinum nanoparticles confined in carbon nanotubes.journal of catalysis,305,19-26. |
| MLA | Guan, Zaihong,et al."An unexpected effect of water on the asymmetric hydrogenation of alpha-ketoesters on platinum nanoparticles confined in carbon nanotubes".journal of catalysis 305(2013):19-26. |
入库方式： OAI收割
来源：大连化学物理研究所
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