中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Dynamic structural changes of perovskite-supported metal catalysts during cyclic redox treatments and effect on catalytic CO oxidation

文献类型:期刊论文

作者Gao Kang1; Wei Mingming2; Qu Zhenping1; Fu Qiang2; Bao Xinhe2
刊名chinese journal of catalysis
出版日期2013-05-01
卷号34期号:5页码:889-897
关键词Perovskite oxide Silver Platinum Redox treatment Structural modification Carbon monoxide oxidation
英文摘要catio3-and batio3-supported ag and pt catalysts were subjected to cyclic oxidation and reduction treatments and their surface structures were investigated using x-ray diffraction (xrd) and x-ray photoelectron spectroscopy (xps). the co oxidation reactions over the ag and pt catalysts showed that the oxidized ag/oxide catalysts performed better in co oxidation than the reduced ones did, whereas the reduced pt/oxide catalysts had higher co oxidation activity than that after oxidation treatment. the xrd and xps measurements revealed that the oxidation treatment helped to improve the dispersion of ag nanoparticles, but their metallic state was retained, which enhanced co oxidation. in contrast, the surfaces of the pt nanoparticles were dominated by pto2 after the oxidation treatment, which lowered the co oxidation activity compared with that of the reduced pt catalyst. (c) 2013, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved.
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, applied ; chemistry, physical ; engineering, chemical
研究领域[WOS]chemistry ; engineering
关键词[WOS]methane ; combustion ; bace1-xpdxo3-delta ; temperatures ; palladium ; oxides ; silver
收录类别SCI
语种英语
WOS记录号WOS:000318744600009
公开日期2015-11-10
源URL[http://159.226.238.44/handle/321008/137818]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Dalian Univ Technol, Sch Environm Sci & Technol, Key Lab Ind Ecol & Environm Engn MOE, Dalian 116024, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
推荐引用方式
GB/T 7714
Gao Kang,Wei Mingming,Qu Zhenping,et al. Dynamic structural changes of perovskite-supported metal catalysts during cyclic redox treatments and effect on catalytic CO oxidation[J]. chinese journal of catalysis,2013,34(5):889-897.
APA Gao Kang,Wei Mingming,Qu Zhenping,Fu Qiang,&Bao Xinhe.(2013).Dynamic structural changes of perovskite-supported metal catalysts during cyclic redox treatments and effect on catalytic CO oxidation.chinese journal of catalysis,34(5),889-897.
MLA Gao Kang,et al."Dynamic structural changes of perovskite-supported metal catalysts during cyclic redox treatments and effect on catalytic CO oxidation".chinese journal of catalysis 34.5(2013):889-897.

入库方式: OAI收割

来源:大连化学物理研究所

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