Dynamic structural changes of perovskite-supported metal catalysts during cyclic redox treatments and effect on catalytic CO oxidation
文献类型:期刊论文
作者 | Gao Kang1; Wei Mingming2; Qu Zhenping1; Fu Qiang2; Bao Xinhe2 |
刊名 | chinese journal of catalysis
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出版日期 | 2013-05-01 |
卷号 | 34期号:5页码:889-897 |
关键词 | Perovskite oxide Silver Platinum Redox treatment Structural modification Carbon monoxide oxidation |
英文摘要 | catio3-and batio3-supported ag and pt catalysts were subjected to cyclic oxidation and reduction treatments and their surface structures were investigated using x-ray diffraction (xrd) and x-ray photoelectron spectroscopy (xps). the co oxidation reactions over the ag and pt catalysts showed that the oxidized ag/oxide catalysts performed better in co oxidation than the reduced ones did, whereas the reduced pt/oxide catalysts had higher co oxidation activity than that after oxidation treatment. the xrd and xps measurements revealed that the oxidation treatment helped to improve the dispersion of ag nanoparticles, but their metallic state was retained, which enhanced co oxidation. in contrast, the surfaces of the pt nanoparticles were dominated by pto2 after the oxidation treatment, which lowered the co oxidation activity compared with that of the reduced pt catalyst. (c) 2013, dalian institute of chemical physics, chinese academy of sciences. published by elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
研究领域[WOS] | chemistry ; engineering |
关键词[WOS] | methane ; combustion ; bace1-xpdxo3-delta ; temperatures ; palladium ; oxides ; silver |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000318744600009 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/137818] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Dalian Univ Technol, Sch Environm Sci & Technol, Key Lab Ind Ecol & Environm Engn MOE, Dalian 116024, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China |
推荐引用方式 GB/T 7714 | Gao Kang,Wei Mingming,Qu Zhenping,et al. Dynamic structural changes of perovskite-supported metal catalysts during cyclic redox treatments and effect on catalytic CO oxidation[J]. chinese journal of catalysis,2013,34(5):889-897. |
APA | Gao Kang,Wei Mingming,Qu Zhenping,Fu Qiang,&Bao Xinhe.(2013).Dynamic structural changes of perovskite-supported metal catalysts during cyclic redox treatments and effect on catalytic CO oxidation.chinese journal of catalysis,34(5),889-897. |
MLA | Gao Kang,et al."Dynamic structural changes of perovskite-supported metal catalysts during cyclic redox treatments and effect on catalytic CO oxidation".chinese journal of catalysis 34.5(2013):889-897. |
入库方式: OAI收割
来源:大连化学物理研究所
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