A comparison on effects of CO2 on La0.8Sr0.2MnO3+delta and La0.6Sr0.4CoO3-delta cathodes
文献类型：期刊论文
| 作者 | Zhao, Zhe1,2,3; Liu, Li1,2,3; Zhang, Xiaomin1,2,3; Wu, Weiming1,2,3; Tu, Baofeng1,2; Ou, Dingrong1,2; Cheng, Mojie1,2 |
| 刊名 | journal of power sources
 |
| 出版日期 | 2013-01-15 |
| 卷号 | 222页码:542-553 |
| 关键词 | Solid oxide fuel cell Carbon dioxide Perovskite Cathode Adsorption model |
| 英文摘要 | the effects and affecting mechanisms of carbon dioxide on oxygen reduction reactions on the la0.6sr0.4coo3-delta (lsc) and la0.8sr0.2mno3+delta (lsm) cathodes have been investigated. the presence of co2 in o-2 flow reduces the lsc and lsm cell performance and increases polarization resistance. co2 impedes oxygen dissociative adsorption on the lsc cathode, whereas co2 inhibits dissociation of adsorbed oxygen molecule or diffusion of o-species on the lsm cathode. co2 adsorption on the lsc cathode obeys temkin model in 550-650 degrees c and freundlich model in 700-800 degrees c. different co2 adsorption behaviors are ascribed to the change in lsc structure and the change in oxygen reduction mechanism. co2 adsorption on the lsm cathode obeys freundlich model in 650-800 degrees c. the differences in the effects and affecting mechanisms of co2 on lsm and lsc are related to their differences in composition and structure. (c) 2012 elsevier by. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | electrochemistry ; energy & fuels |
| 研究领域[WOS] | electrochemistry ; energy & fuels |
| 关键词[WOS] | oxide fuel-cells ; porous la1-xsrxcoo3-delta electrodes ; oxygen-surface exchange ; electrochemical performance ; electrocatalytic properties ; impedance spectroscopy ; composite cathodes ; ceria electrolytes ; design principles ; perovskite oxides |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000311129900076 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137836]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Dalian Natl Lab Clean Energy, Div Fuel Cells, Dalian, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Zhe,Liu, Li,Zhang, Xiaomin,et al. A comparison on effects of CO2 on La0.8Sr0.2MnO3+delta and La0.6Sr0.4CoO3-delta cathodes[J]. journal of power sources,2013,222:542-553. |
| APA | Zhao, Zhe.,Liu, Li.,Zhang, Xiaomin.,Wu, Weiming.,Tu, Baofeng.,...&Cheng, Mojie.(2013).A comparison on effects of CO2 on La0.8Sr0.2MnO3+delta and La0.6Sr0.4CoO3-delta cathodes.journal of power sources,222,542-553. |
| MLA | Zhao, Zhe,et al."A comparison on effects of CO2 on La0.8Sr0.2MnO3+delta and La0.6Sr0.4CoO3-delta cathodes".journal of power sources 222(2013):542-553. |
入库方式： OAI收割
来源：大连化学物理研究所
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