Lithium borohydride-melamine complex as a promising material for chemical hydrogen storage
文献类型:期刊论文
作者 | Liu, Lin; Hu, Daqiang; He, Teng; Zhang, Yao; Wu, Guotao; Chu, Hailiang; Wang, Peikun; Xiong, Zhitao; Chen, Ping |
刊名 | journal of alloys and compounds
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出版日期 | 2013-03-05 |
卷号 | 552页码:98-101 |
关键词 | Chemical hydrogen storage Lithium borohydride-melamine complex hydride Protic hydrogen Hydridic hydrogen |
英文摘要 | a complex hydride, 3libh(4)center dot c3n6h6, crystallizing in monoclinic structure with lattice parameters of a = 17.4701 angstrom, b = 17.6332 angstrom, c = 4.1749 angstrom, beta = 99.7453 degrees and v = 1267.54 angstrom(3), was synthesized by solid reaction between libh4 and c3n6h6. 3libh(4)center dot c3n6h6 starts to evolve hydrogen at 100 degrees c, which is 190 degrees c lower than that of pristine libh4. combination of protic hydrogen of [bh4](-) and hydridic hydrogen of nh in 3libh(4)center dot c3n6h6 may greatly improve the dehydrogenation properties, and totally 7.83 wt.% h-2 can be released from 3libh(4)center dot c3n6h6 in the temperature range of 100-340 degrees c. (c0 2012 elsevier b. v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, physical ; materials science, multidisciplinary ; metallurgy & metallurgical engineering |
研究领域[WOS] | chemistry ; materials science ; metallurgy & metallurgical engineering |
关键词[WOS] | dehydrogenation behavior ; libh4 ; destabilization ; composites ; al ; reversibility ; stability ; powder ; mgh2 ; b-11 |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000313653300017 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/137853] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clear Energy, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Lin,Hu, Daqiang,He, Teng,et al. Lithium borohydride-melamine complex as a promising material for chemical hydrogen storage[J]. journal of alloys and compounds,2013,552:98-101. |
APA | Liu, Lin.,Hu, Daqiang.,He, Teng.,Zhang, Yao.,Wu, Guotao.,...&Chen, Ping.(2013).Lithium borohydride-melamine complex as a promising material for chemical hydrogen storage.journal of alloys and compounds,552,98-101. |
MLA | Liu, Lin,et al."Lithium borohydride-melamine complex as a promising material for chemical hydrogen storage".journal of alloys and compounds 552(2013):98-101. |
入库方式: OAI收割
来源:大连化学物理研究所
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