Comparative study of methanol adsorption and electro-oxidation on carbon-supported platinum in acidic and alkaline electrolytes
文献类型：期刊论文
| 作者 | Jing, Mingyi1,2; Jiang, Luhua1; Yi, Baolian1; Sun, Gongquan1 |
| 刊名 | journal of electroanalytical chemistry
 |
| 出版日期 | 2013 |
| 卷号 | 688页码:172-179 |
| 关键词 | Acid electrolyte Alkaline electrolyte Methanol electro-oxidation reaction Kinetics Adsorption Carbon-supported platinum |
| 英文摘要 | methanol electro-oxidation reaction over carbon-supported platinum nanoparticles, including methanol adsorption, apparent reaction order and activation energy, in acidic and alkaline media was investigated comparatively. the results show that the rate constant for methanol adsorption in 1 m naoh is significantly higher than that in 0.5 m h2so4 at the relatively low potential and the coad removal in alkaline media is easier, due to the availability of oxygen-containing species, than in acidic media at the same potential. the apparent activation energy for the mor in alkaline media is 25.3-14.6 kj mol(-1), significantly lower than that in acidic media (34.9-28.5 kj mol(-1)). the better mor activity of pt/c in alkaline media is attributed to the faster methanol adsorption and the availability of oxygen-containing species. crown copyright (c) 2012 published by elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; electrochemistry |
| 研究领域[WOS] | chemistry ; electrochemistry |
| 关键词[WOS] | electrochemical mass-spectrometry ; fuel-cell ; polymer-electrolyte ; oxygen reduction ; pt-ru ; oxidation ; catalysts ; surface ; dependence ; mechanism |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000317158800028 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137865]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Fuel Cell & Battery Div, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jing, Mingyi,Jiang, Luhua,Yi, Baolian,et al. Comparative study of methanol adsorption and electro-oxidation on carbon-supported platinum in acidic and alkaline electrolytes[J]. journal of electroanalytical chemistry,2013,688:172-179. |
| APA | Jing, Mingyi,Jiang, Luhua,Yi, Baolian,&Sun, Gongquan.(2013).Comparative study of methanol adsorption and electro-oxidation on carbon-supported platinum in acidic and alkaline electrolytes.journal of electroanalytical chemistry,688,172-179. |
| MLA | Jing, Mingyi,et al."Comparative study of methanol adsorption and electro-oxidation on carbon-supported platinum in acidic and alkaline electrolytes".journal of electroanalytical chemistry 688(2013):172-179. |
入库方式： OAI收割
来源：大连化学物理研究所
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