Thermodynamic Properties of Nd(Gly)(2)Cl-3 center dot 3H(2)O and Pr(Ala)(3)Cl-3 center dot 3H(2)O
文献类型：期刊论文
| 作者 | Liu Bei-Ping2; Tan Zhi-Cheng1 |
| 刊名 | acta physico-chimica sinica
 |
| 出版日期 | 2013 |
| 卷号 | 29期号:1页码:17-22 |
| 关键词 | Rare-earth complex Adiabatic calorimetry Low-temperature heat capacity Thermodynamic function Thermogravimetric analysis Solution-reaction isoperibol calorimeter Standard molar enthalpy of formation |
| 英文摘要 | the heat capacities of rare earth complexes, nd(gly)(2)cl-3 center dot 3h(2)o and pr(ala)(3)cl-3 center dot 3h(2)o were measured with a high-precision automatic adiabatic calorimeter in the temperature range from 80 to 357 k for nd(gly)(2)cl-3 center dot 3h(2)o, and from 80 to 374 k for pr(ala)(3)cl-3 center dot 3h(2)o. the thermodynamic functions (h-t-h-298.15) and (s-t-s-298.15) relative to the reference temperature 298.15 k of the two compounds were calculated based on experimental heat capacity data. possible mechanisms of thermal decompositions were proposed according to the thermogravimetric (tg) analysis. based on the measurements of dissolution enthalpies using a solution-reaction isoperibol calorimeter, the standard molar enthalpies of formation were calculated in terms of a designed hess thermochemical cycle. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | temperature heat-capacity ; standard molar enthalpy ; calorimeter ; crystalline ; complex ; acid |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000312711700003 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137866]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Liaoning Prov, Peoples R China 2.Hunan Univ Arts & Sci, Coll Chem & Chem Engn, Changde 415000, Hunan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu Bei-Ping,Tan Zhi-Cheng. Thermodynamic Properties of Nd(Gly)(2)Cl-3 center dot 3H(2)O and Pr(Ala)(3)Cl-3 center dot 3H(2)O[J]. acta physico-chimica sinica,2013,29(1):17-22. |
| APA | Liu Bei-Ping,&Tan Zhi-Cheng.(2013).Thermodynamic Properties of Nd(Gly)(2)Cl-3 center dot 3H(2)O and Pr(Ala)(3)Cl-3 center dot 3H(2)O.acta physico-chimica sinica,29(1),17-22. |
| MLA | Liu Bei-Ping,et al."Thermodynamic Properties of Nd(Gly)(2)Cl-3 center dot 3H(2)O and Pr(Ala)(3)Cl-3 center dot 3H(2)O".acta physico-chimica sinica 29.1(2013):17-22. |
入库方式： OAI收割
来源：大连化学物理研究所
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