An efficient and scalable room temperature aerobic alcohol oxidation catalyzed by iron chloride hexahydrate/mesoporous silica supported TEMPO
文献类型：期刊论文
| 作者 | Wang, Lianyue1; Li, Jun1; Zhao, Xiaoping2; Lv, Ying1; Zhang, Hengyun1; Gao, Shuang1 |
| 刊名 | tetrahedron
 |
| 出版日期 | 2013-07-29 |
| 卷号 | 69期号:30页码:6041-6045 |
| 关键词 | Alcohol oxidation Iron chloride Molecular oxygen 2 (TEMPO) SBA-15 2 6 6-Tetramethylpiperidine N-Oxyl |
| 英文摘要 | an efficient room temperature catalytic system fecl3 center dot 6h(2)o/sba-15-tempo/nano2 for the oxidation of alcohols with dioxygen or air as terminal oxidant'has been developed. various alcohols were oxidized at a low catalyst loading (0.1-1 mol %) to the corresponding carbonyl compounds in good to excellent yields. for the oxidation of benzyl alcohol, the excellent turn-over frequency (top) of 81.4 h(-1) was achieved (turn-over number (ton) up to 9770). the catalyst sba-15-tempo can be reused for 10 reaction runs without significant loss of catalytic activity. in addition, the two components fecl3 center dot 6h(2)o and sba-15-tempo can also be reused for at least four reaction runs without appreciable loss of catalytic activity. in the case of large-scale experiment for the oxidation of benzyl alcohol, the desired product benzaldehyde was obtained in 94.5% yield. (c) 2013 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | transition-metal-free ; poly(ethylene glycol)-supported tempo ; generated acidic environment ; phase beckmann rearrangement ; sba-15 mesoporous materials ; selective oxidation ; mild conditions ; secondary alcohols ; cyclohexanone oxime ; nitroxyl radicals |
| 收录类别 | SCI ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000321474100003 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/137960]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Natl Lab Clean Energy, DNL, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Shaanxi Yanchang Petr Grp Co Ltd, Xian 716000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Lianyue,Li, Jun,Zhao, Xiaoping,et al. An efficient and scalable room temperature aerobic alcohol oxidation catalyzed by iron chloride hexahydrate/mesoporous silica supported TEMPO[J]. tetrahedron,2013,69(30):6041-6045. |
| APA | Wang, Lianyue,Li, Jun,Zhao, Xiaoping,Lv, Ying,Zhang, Hengyun,&Gao, Shuang.(2013).An efficient and scalable room temperature aerobic alcohol oxidation catalyzed by iron chloride hexahydrate/mesoporous silica supported TEMPO.tetrahedron,69(30),6041-6045. |
| MLA | Wang, Lianyue,et al."An efficient and scalable room temperature aerobic alcohol oxidation catalyzed by iron chloride hexahydrate/mesoporous silica supported TEMPO".tetrahedron 69.30(2013):6041-6045. |
入库方式： OAI收割
来源：大连化学物理研究所
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