Aggregation-Induced Enhancement Effect of Gold Nanoparticles on Triplet Excited State
文献类型:期刊论文
作者 | Yang, Wen; Liu, Kunhui; Song, Di; Du, Qian; Wang, Rennian; Su, Hongmei |
刊名 | journal of physical chemistry c
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出版日期 | 2013-12-26 |
卷号 | 117期号:51页码:27088-27095 |
英文摘要 | remarkable optical properties are posed with gold nanoparticles (aunps) due to the excitation of localized surface plasmon resonances, which makes aunps affect strongly both the ground state and the excited state of adjacent organic molecules. compared with the ground state, the effect of aunps on excited state of organic molecules is not always fully understood. here, we performed transient uv-vis absorption experiments to monitor the triplet excited state formation of three cationic dyes and one anionic dye in the presence of two types of gold nanoparticles: the citrate-stabilized aunps and atp-protected aunps. it is found that the three cationic dyes can cause efficient aggregation of citrate-stabilized aunps, leading to aunps aggregates with varied size, whereas the atp-protected aunps can be sustained in the monodispersed state. by comparing the circumstances of aggregated aunps and monodispersed aunps, we demonstrate that the enhancement effect on triplet excited state formation results from the aggregation of gold nanoparticles and depends on the aggregation size. these findings reveal the aggregation induced plasmon field interaction of aunps with excited state population dynamics and may enable new applications of aggregated metal nanoparticles, where aggregates can serve as stronger plasmonic nanoantennas. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
关键词[WOS] | fluorescence enhancement ; raman-scattering ; spectroscopy ; assemblies ; plasmonics ; nucleation ; silver ; size |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000329331300029 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/137985] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci BNLMS, Inst Chem, State Key Lab Mol React Dynam, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Yang, Wen,Liu, Kunhui,Song, Di,et al. Aggregation-Induced Enhancement Effect of Gold Nanoparticles on Triplet Excited State[J]. journal of physical chemistry c,2013,117(51):27088-27095. |
APA | Yang, Wen,Liu, Kunhui,Song, Di,Du, Qian,Wang, Rennian,&Su, Hongmei.(2013).Aggregation-Induced Enhancement Effect of Gold Nanoparticles on Triplet Excited State.journal of physical chemistry c,117(51),27088-27095. |
MLA | Yang, Wen,et al."Aggregation-Induced Enhancement Effect of Gold Nanoparticles on Triplet Excited State".journal of physical chemistry c 117.51(2013):27088-27095. |
入库方式: OAI收割
来源:大连化学物理研究所
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