Mode specific photodissociation of CS2+ via the A(2)Pi(u) state: a time-sliced velocity map imaging study
文献类型：期刊论文
| 作者 | Zhang, Cuimei1,2,3; Li, Jialin1,2; Zhang, Qun1,2; Chen, Yang1,2; Huang, Cunshun3; Yang, Xueming3 |
| 刊名 | physical chemistry chemical physics
 |
| 出版日期 | 2012 |
| 卷号 | 14期号:7页码:2468-2474 |
| 英文摘要 | the vibrationally mediated photodissociation of cs2+ cations via the a(2)pi(u)(nu(1),nu(2),0) state has been studied by means of the velocity map ion imaging technique. the measurements were made with a double resonance strategy. the cs2+ cations were prepared by a (3 + 1) resonance enhanced multiphoton ionization method. the photo-fragment excitation spectrum of s+ was recorded by scanning the photolysis laser via the a(2)pi(u)(nu(1),nu(2),0) state. by fixing the photolysis laser wavelength at the specific vibrational state, the (1 + 1) photodissociation images of s+ photofragments from numerous vibrationally mediated states have been accumulated. the translational energy release spectra derived from the resulting images imply that the co-fragments, cs radicals, are both vibrationally and rotationally excited. the one-photon photodissociation without the vibrational state selection has also been performed. comparing the vibrationally mediated photodissociation with one-photon photodissociation observations, clear evidence of vibrational state control of the photodissociation process is observed. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical ; physics, atomic, molecular & chemical |
| 研究领域[WOS] | chemistry ; physics |
| 关键词[WOS] | pulsed-field ionization ; 2-photon absorption-spectroscopy ; enhanced multiphoton ionization ; collision-induced dissociation ; carbon-disulfide ; photoelectron bands ; photo-ionization ; electron-impact ; molecular ion ; dynamics |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000299505400044 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138014]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China 2.Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Anhui, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Cuimei,Li, Jialin,Zhang, Qun,et al. Mode specific photodissociation of CS2+ via the A(2)Pi(u) state: a time-sliced velocity map imaging study[J]. physical chemistry chemical physics,2012,14(7):2468-2474. |
| APA | Zhang, Cuimei,Li, Jialin,Zhang, Qun,Chen, Yang,Huang, Cunshun,&Yang, Xueming.(2012).Mode specific photodissociation of CS2+ via the A(2)Pi(u) state: a time-sliced velocity map imaging study.physical chemistry chemical physics,14(7),2468-2474. |
| MLA | Zhang, Cuimei,et al."Mode specific photodissociation of CS2+ via the A(2)Pi(u) state: a time-sliced velocity map imaging study".physical chemistry chemical physics 14.7(2012):2468-2474. |
入库方式： OAI收割
来源：大连化学物理研究所
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