Photocatalytic Water Oxidation on BiVO4 with the Electrocatalyst as an Oxidation Cocatalyst: Essential Relations between Electrocatalyst and Photocatalyst
文献类型：期刊论文
| 作者 | Wang, Donge1,2; Li, Rengui1,2; Zhu, Jian1,2; Shi, Jingying1; Han, Jingfeng1,2; Zong, Xu1; Li, Can1 |
| 刊名 | journal of physical chemistry c
 |
| 出版日期 | 2012-03-01 |
| 卷号 | 116期号:8页码:5082-5089 |
| 英文摘要 | the oxygen evolution is kinetically the key step in the photocatalytic water splitting. cocatalysts could lower the activation potential for o-2 evolution. however, the cocatalyst for o-2 evolution has been less investigated, and few effective cocatalysts were reported. this paper reports that the o-2 evolution rate of photocatalytic water splitting under visible light irradiation can be significantly enhanced when the electrocatalyst cobalt phosphate (denoted as copi) was deposited on bivo4. the photocurrent density is also greatly enhanced by loading copi on bivo4 electrode, and this enhancement in performance shows the similar trend between the photocatalytic activity and photocurrent density. we also found that this tendency is true for bivo4 loaded with a series of different electrocatalysts as the cocatalysts. these results demonstrate that an effective electrocatalyst of water oxidation can be also an effective cocatalyst for o-2 evolution from photocatalytic water oxidation. by depositing the copi as the oxidation cocatalyst and pt as the reduction cocatalyst on an yttrium-doped bivo4 (bi0.5y0.5vo4), overall water splitting reaction to h-2 and o-2 was realized. our work also reveals the essential relations between photocatalysis and electrocatalysis in water splitting reaction. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
| 关键词[WOS] | oxygen-evolving catalyst ; (ga1-xznx)(n1-xox) solid-solution ; visible-light irradiation ; hydrogen-production ; oxide electrode ; solar-energy ; evolution ; h-2 ; decomposition ; o-2 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000300911600021 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138015]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Donge,Li, Rengui,Zhu, Jian,et al. Photocatalytic Water Oxidation on BiVO4 with the Electrocatalyst as an Oxidation Cocatalyst: Essential Relations between Electrocatalyst and Photocatalyst[J]. journal of physical chemistry c,2012,116(8):5082-5089. |
| APA | Wang, Donge.,Li, Rengui.,Zhu, Jian.,Shi, Jingying.,Han, Jingfeng.,...&Li, Can.(2012).Photocatalytic Water Oxidation on BiVO4 with the Electrocatalyst as an Oxidation Cocatalyst: Essential Relations between Electrocatalyst and Photocatalyst.journal of physical chemistry c,116(8),5082-5089. |
| MLA | Wang, Donge,et al."Photocatalytic Water Oxidation on BiVO4 with the Electrocatalyst as an Oxidation Cocatalyst: Essential Relations between Electrocatalyst and Photocatalyst".journal of physical chemistry c 116.8(2012):5082-5089. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。