Aerobic oxidation of alcohols using a novel combination of N-hydroxyphthalimide (NHPI) and CuBr
文献类型:期刊论文
作者 | Yang, Gang1,2; Wang, Lianyue1,3; Li, Jun1; Zhang, Yi1; Dong, Xiaoli2; Lv, Ying1; Gao, Shuang1 |
刊名 | research on chemical intermediates
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出版日期 | 2012-03-01 |
卷号 | 38期号:3-5页码:775-783 |
关键词 | Oxidation Alcohol NHPI Copper Oxygen |
英文摘要 | a new catalytic system for oxidation of alcohols with oxygen by n-hydroxyphthalimide (nhpi) combined with cubr has been developed. the reaction results showed that this catalytic system can effectively catalyze the oxidation of alcohols to the corresponding carboxylic acids or ketones. we obtained 100% selectivity for acetophenone at 94.2% conversion of phenylethanol at 75 degrees c for 20 h. a mechanism of oxidation of alcohols catalyzed by nhpi/cubr was proposed. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, multidisciplinary |
研究领域[WOS] | chemistry |
关键词[WOS] | vanadium cocatalysts ; carbonyl-compounds ; mild conditions ; atom economy ; dioxygen ; phthalimide ; catalysis ; oxygen |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000302146500008 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/138023] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Dalian Polytech Univ, Sch Chem & Mat, Dalian 116034, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Yang, Gang,Wang, Lianyue,Li, Jun,et al. Aerobic oxidation of alcohols using a novel combination of N-hydroxyphthalimide (NHPI) and CuBr[J]. research on chemical intermediates,2012,38(3-5):775-783. |
APA | Yang, Gang.,Wang, Lianyue.,Li, Jun.,Zhang, Yi.,Dong, Xiaoli.,...&Gao, Shuang.(2012).Aerobic oxidation of alcohols using a novel combination of N-hydroxyphthalimide (NHPI) and CuBr.research on chemical intermediates,38(3-5),775-783. |
MLA | Yang, Gang,et al."Aerobic oxidation of alcohols using a novel combination of N-hydroxyphthalimide (NHPI) and CuBr".research on chemical intermediates 38.3-5(2012):775-783. |
入库方式: OAI收割
来源:大连化学物理研究所
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