Heterogeneous Bimetallic Pt-Sn/gamma-Al2O3 Catalyzed N-Alkylation of Amines: Efficient Synthesis of Secondary and Tertiary Amines
文献类型：期刊论文
| 作者 | He Wei; He Songbo; Sun Chenglin; Wu Kaikai; Wang Liandi; Yu Zhengkun |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2012-04-01 |
| 卷号 | 33期号:4页码:717-722 |
| 关键词 | platinum tin alumina supported catalyst borrowing hydrogen heterogeneous catalysis N-alkylation amine alcohol |
| 英文摘要 | n-alkylation of amines with alcohols through a borrowing hydrogen strategy is a green route to amines. heterogeneous bimetallic pt-sn/gamma-al2o3 catalyzed the reactions of primary (secondary) amines with alcohols in the absence of external hydrogen source, efficiently affording secondary (tertiary) amines with water and a small amount of imines as the by-products. various functional groups in the substrates were tolerated in the catalytic system. the pt-sn/gamma-al2o3 catalyst was easily recycled, suggesting its potential application in the production of secondary and tertiary amines. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | asterisk-ir complex ; borrowing hydrogen ; organic-synthesis ; alcohols ; sulfonamides ; heterocyclization ; dehydrogenation ; activation ; amination ; versatile |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000303360300020 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138057]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | He Wei,He Songbo,Sun Chenglin,et al. Heterogeneous Bimetallic Pt-Sn/gamma-Al2O3 Catalyzed N-Alkylation of Amines: Efficient Synthesis of Secondary and Tertiary Amines[J]. chinese journal of catalysis,2012,33(4):717-722. |
| APA | He Wei,He Songbo,Sun Chenglin,Wu Kaikai,Wang Liandi,&Yu Zhengkun.(2012).Heterogeneous Bimetallic Pt-Sn/gamma-Al2O3 Catalyzed N-Alkylation of Amines: Efficient Synthesis of Secondary and Tertiary Amines.chinese journal of catalysis,33(4),717-722. |
| MLA | He Wei,et al."Heterogeneous Bimetallic Pt-Sn/gamma-Al2O3 Catalyzed N-Alkylation of Amines: Efficient Synthesis of Secondary and Tertiary Amines".chinese journal of catalysis 33.4(2012):717-722. |
入库方式： OAI收割
来源：大连化学物理研究所
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