Preparation and properties of Nafion/SiO2 composite membrane derived via in situ sol-gel reaction: size controlling and size effects of SiO2 nano-particles
文献类型：期刊论文
| 作者 | Ke, Chang-Chun1,2; Li, Xiao-Jin1; Qu, Shu-Guo1,2; Shao, Zhi-Gang1; Yi, Bao-Lian1 |
| 刊名 | polymers for advanced technologies
 |
| 出版日期 | 2012 |
| 卷号 | 23期号:1页码:92-98 |
| 关键词 | proton exchange membrane fuel cell in situ sol-gel Na?on SiO2 composite membrane SiO2 nano-particle size effect |
| 英文摘要 | a novel technique in controlling the size of sio2 nano-particles in the preparation of nafion/sio2 composite membranes via in situ solgel method, as well as the effects of nano-particle size on membrane properties and cell performance, is reported in this paper. nafion/sio2 composite membranes containing sio2 nano-particles with four different diameters (5 +/- 0.5, 7 +/- 0.5, 10 +/- 1, and 15 +/- 2nm) are fabricated by altering the reactant concentrations during in situ solgel reaction. sequentially, size effects of sio2 nano-particles on membrane properties and cell performance are investigated by sem/edax, tem, tga, mechanical tensile, and single cell tests, etc. the results suggest that 10nm is a critical diameter for sio2 incorporated into nafion matrix, exhibiting desirable physico-chemical properties for operation at elevated temperature and low humidity. at 110 degrees c and 59% rh, the output voltage of the cell equipped with nafion/sio2 (10nm) obtains an output voltage of 0.625v at 600ma/cm2, which is 50mv higher than that of unmodified nafion. copyright (c) 2010 john wiley & sons, ltd. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | polymer science |
| 研究领域[WOS] | polymer science |
| 关键词[WOS] | proton-exchange membrane ; high-temperature operation ; pem fuel-cells ; perfluorosulfonic acid ionomer ; silicon-oxide phase ; microstructural evolution ; 100-degrees-c ; nanospheres ; nafion(r) ; dioxide |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000298263500012 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138060]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Fuel Cell Syst & Engn, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ke, Chang-Chun,Li, Xiao-Jin,Qu, Shu-Guo,et al. Preparation and properties of Nafion/SiO2 composite membrane derived via in situ sol-gel reaction: size controlling and size effects of SiO2 nano-particles[J]. polymers for advanced technologies,2012,23(1):92-98. |
| APA | Ke, Chang-Chun,Li, Xiao-Jin,Qu, Shu-Guo,Shao, Zhi-Gang,&Yi, Bao-Lian.(2012).Preparation and properties of Nafion/SiO2 composite membrane derived via in situ sol-gel reaction: size controlling and size effects of SiO2 nano-particles.polymers for advanced technologies,23(1),92-98. |
| MLA | Ke, Chang-Chun,et al."Preparation and properties of Nafion/SiO2 composite membrane derived via in situ sol-gel reaction: size controlling and size effects of SiO2 nano-particles".polymers for advanced technologies 23.1(2012):92-98. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。