Ionothermal synthesis process for aluminophosphate molecular sieves in the mixed water/ionic liquid system
文献类型：期刊论文
| 作者 | Zhao, Zhenchao1; Zhang, Weiping2; Xu, Renshun1; Han, Xiuwen1; Tian, Zhijian1; Bao, Xinhe1 |
| 刊名 | dalton transactions
 |
| 出版日期 | 2012 |
| 卷号 | 41期号:3页码:990-994 |
| 英文摘要 | the synthesis process of aluminophosphate alpo4-11 molecular sieve in the mixed water/1-butyl-3-methylimidazolium bromide ([bmim]br) ionic liquid was investigated by xrd, multinuclear solid-state nmr, scanning electron microscopy (sem) and x-ray energy dispersive spectroscopy (eds). it was observed that a tablet phase, named siz-2, was formed at the early stage of crystallization. during crystallization metastable siz-2 with an incompletely condensed framework phosphorus disappeared gradually, and the phosphorous species became fully condensed through hydroxyl reaction with tetrahedral aluminum to form thermodynamically stable alpo4-11 in the final product. it was found that [bmim] br, acting as the structure-directing agent, was occluded into the alpo4-11 channel. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, inorganic & nuclear |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | ionic liquids ; inorganic materials ; nmr ; alpo4-11 ; template ; solvent ; amines ; water |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000298753800038 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138095]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Zhenchao,Zhang, Weiping,Xu, Renshun,et al. Ionothermal synthesis process for aluminophosphate molecular sieves in the mixed water/ionic liquid system[J]. dalton transactions,2012,41(3):990-994. |
| APA | Zhao, Zhenchao,Zhang, Weiping,Xu, Renshun,Han, Xiuwen,Tian, Zhijian,&Bao, Xinhe.(2012).Ionothermal synthesis process for aluminophosphate molecular sieves in the mixed water/ionic liquid system.dalton transactions,41(3),990-994. |
| MLA | Zhao, Zhenchao,et al."Ionothermal synthesis process for aluminophosphate molecular sieves in the mixed water/ionic liquid system".dalton transactions 41.3(2012):990-994. |
入库方式： OAI收割
来源：大连化学物理研究所
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