SiO2-supported bimetallic Rh-Co catalysts derived from [Rh(C0)(2)Cl](2) and cobalt carbonyls
文献类型：期刊论文
| 作者 | Huang, L; Xu, Y |
| 刊名 | catalysis letters
 |
| 出版日期 | 1998 |
| 卷号 | 53期号:3-4页码:177-183 |
| 关键词 | [Rh(CO)(2)Cl](2) cobalt carbonyl SiO2 bimetallic catalyst co-impregnation |
| 英文摘要 | according to the results of ir characterization and catalytic study in ethylene hydroformylation, bimetallic rh-co catalysts can be efficiently prepared from [rh(co)(2)cl](2) and cobalt carbonyls by co-impregnation on sio2. the reaction of co-2(co)(8) with [rh(co)(2)cl](2) (rh:co = 1 :3 atomic ratio) gives rapidly rhco3(co)(12) on the surface of sio2. although co-4(co)(12) is not reactive with [rh(co)(2)cl](2) on sio2 to form directly rhco3(co)(12), an equivalent bimetallic catalyst can be easily obtained from ([rh(co)(2)cl](2) + co-4(co)(12))/sio2 or its derivative (rh+ + co2+)sio2 (rh:co = 1 :3 atomic ratio) under reducing conditions. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | surface organometallic chemistry
; pt-re/al2o3 catalysts
; redox reactions
; rhco3 clusters
; ft-ir
; hydroformylation
; mgo
; hydrogenolysis
; hydrogenation
; |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000075586000008 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138109]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, L,Xu, Y. SiO2-supported bimetallic Rh-Co catalysts derived from [Rh(C0)(2)Cl](2) and cobalt carbonyls[J]. catalysis letters,1998,53(3-4):177-183. |
| APA | Huang, L,&Xu, Y.(1998).SiO2-supported bimetallic Rh-Co catalysts derived from [Rh(C0)(2)Cl](2) and cobalt carbonyls.catalysis letters,53(3-4),177-183. |
| MLA | Huang, L,et al."SiO2-supported bimetallic Rh-Co catalysts derived from [Rh(C0)(2)Cl](2) and cobalt carbonyls".catalysis letters 53.3-4(1998):177-183. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。