Methane adsorption on Rh/Al2O3
文献类型：期刊论文
| 作者 | Wang, DZ; Dewaele, O; Froment, GF |
| 刊名 | journal of molecular catalysis a-chemical
 |
| 出版日期 | 1998-12-21 |
| 卷号 | 136期号:3页码:301-309 |
| 关键词 | methane adsorption structure-sensitive reaction oxygen adsorption adsorption rates |
| 英文摘要 | the rates of ch4 adsorption on a supported rh catalyst after different treatments of the surface were measured by means of a temporal-analysis-of-products (tap) reactor. the catalyst was kept in a well-defined state during adsorption experiments by using a very small pulse size. ch4 adsorbs on reduced sites. the highest adsorption rate was observed with a catalyst which had undergone an oxygen treatment above 800 k. ch4 adsorption activity is strongly reduced by the complete removal of oxygen from the catalyst. the results were compared with the adsorption rates of o-2 and h2o and with the activities for c2h6 hydrogenolysis and c2h4 hydrogenation. ch4 adsorption is proposed to be structure sensitive. (c) 1998 elsevier science b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | partial oxidation ; synthesis gas ; dissociative chemisorption ; activated chemisorption ; catalysts ; rhodium ; kinetics ; hydrogen ; ch4 ; surfaces |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000077201700011 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138157]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.State Univ Ghent, Petrochem Tech Lab, B-9000 Ghent, Belgium |
| 推荐引用方式 GB/T 7714 | Wang, DZ,Dewaele, O,Froment, GF. Methane adsorption on Rh/Al2O3[J]. journal of molecular catalysis a-chemical,1998,136(3):301-309. |
| APA | Wang, DZ,Dewaele, O,&Froment, GF.(1998).Methane adsorption on Rh/Al2O3.journal of molecular catalysis a-chemical,136(3),301-309. |
| MLA | Wang, DZ,et al."Methane adsorption on Rh/Al2O3".journal of molecular catalysis a-chemical 136.3(1998):301-309. |
入库方式： OAI收割
来源：大连化学物理研究所
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