Electrochemical reduction of oxygen on a strontium doped lanthanum manganite electrode
文献类型:期刊论文
作者 | Jiang, Y; Wang, SZ; Zhang, YH; Yan, JW; Li, WZ |
刊名 | solid state ionics
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出版日期 | 1998-07-01 |
卷号 | 110期号:1-2页码:111-119 |
关键词 | electrochemical reduction of oxygen solid oxide fuel cell strontium doped lanthanum manganite YSZ+LSM composite electrode |
英文摘要 | the electrochemical reduction of oxygen on a strontium doped lanthanum manganite (lsm) electrode has been studied by both low field and high field polarization at various partial pressures of oxygen and temperature. the reciprocal of the electrode resistance (t/r(e)) was found to be 1/4 power dependent on the partial pressure of oxygen at high temperatures, and became p(o2) independent at low temperatures. two temperature dependence regions with an activation energy of similar to 160 kj mol(-1) in the high temperature region and similar to 120 kj mol(-1) in the low temperature region were determined. both the anodic and cathodic charge transfer coefficients were found to be unity at temperatures above 923 k. based on the results for the temperature and oxygen partial pressure dependence, an electrochemical mechanism for oxygen reduction on the lsm has been proposed. (c) 1998 elsevier science b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical ; physics, condensed matter |
研究领域[WOS] | chemistry ; physics |
关键词[WOS] | oxide fuel-cells ; impedance spectroscopy ; polarization phenomena ; cathodic polarization ; stabilized zirconia ; la1-xsrxmno3 ; kinetics |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000074649300014 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/138184] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Jiang, Y,Wang, SZ,Zhang, YH,et al. Electrochemical reduction of oxygen on a strontium doped lanthanum manganite electrode[J]. solid state ionics,1998,110(1-2):111-119. |
APA | Jiang, Y,Wang, SZ,Zhang, YH,Yan, JW,&Li, WZ.(1998).Electrochemical reduction of oxygen on a strontium doped lanthanum manganite electrode.solid state ionics,110(1-2),111-119. |
MLA | Jiang, Y,et al."Electrochemical reduction of oxygen on a strontium doped lanthanum manganite electrode".solid state ionics 110.1-2(1998):111-119. |
入库方式: OAI收割
来源:大连化学物理研究所
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