中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Electrochemical reduction of oxygen on a strontium doped lanthanum manganite electrode

文献类型:期刊论文

作者Jiang, Y; Wang, SZ; Zhang, YH; Yan, JW; Li, WZ
刊名solid state ionics
出版日期1998-07-01
卷号110期号:1-2页码:111-119
关键词electrochemical reduction of oxygen solid oxide fuel cell strontium doped lanthanum manganite YSZ+LSM composite electrode
英文摘要the electrochemical reduction of oxygen on a strontium doped lanthanum manganite (lsm) electrode has been studied by both low field and high field polarization at various partial pressures of oxygen and temperature. the reciprocal of the electrode resistance (t/r(e)) was found to be 1/4 power dependent on the partial pressure of oxygen at high temperatures, and became p(o2) independent at low temperatures. two temperature dependence regions with an activation energy of similar to 160 kj mol(-1) in the high temperature region and similar to 120 kj mol(-1) in the low temperature region were determined. both the anodic and cathodic charge transfer coefficients were found to be unity at temperatures above 923 k. based on the results for the temperature and oxygen partial pressure dependence, an electrochemical mechanism for oxygen reduction on the lsm has been proposed. (c) 1998 elsevier science b.v. all rights reserved.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical ; physics, condensed matter
研究领域[WOS]chemistry ; physics
关键词[WOS]oxide fuel-cells ; impedance spectroscopy ; polarization phenomena ; cathodic polarization ; stabilized zirconia ; la1-xsrxmno3 ; kinetics
收录类别SCI
语种英语
WOS记录号WOS:000074649300014
公开日期2015-11-10
源URL[http://159.226.238.44/handle/321008/138184]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Jiang, Y,Wang, SZ,Zhang, YH,et al. Electrochemical reduction of oxygen on a strontium doped lanthanum manganite electrode[J]. solid state ionics,1998,110(1-2):111-119.
APA Jiang, Y,Wang, SZ,Zhang, YH,Yan, JW,&Li, WZ.(1998).Electrochemical reduction of oxygen on a strontium doped lanthanum manganite electrode.solid state ionics,110(1-2),111-119.
MLA Jiang, Y,et al."Electrochemical reduction of oxygen on a strontium doped lanthanum manganite electrode".solid state ionics 110.1-2(1998):111-119.

入库方式: OAI收割

来源:大连化学物理研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。