Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides
文献类型：期刊论文
| 作者 | Guerrero-Ruiz, A; Zhang, Y; Bachiller-Baeza, B; Rodriguez-Ramos, I |
| 刊名 | catalysis letters
 |
| 出版日期 | 1998 |
| 卷号 | 55期号:3-4页码:165-168 |
| 关键词 | molybdenum nitride catalysts crotonaldehyde hydrogenation |
| 英文摘要 | the gas-phase hydrogenation of crotonaldehyde has been performed over unsupported mo(2)n and over mo(2)n supported on two carbonaceous materials, an activated carbon (ac) and a high surface area graphite (g). these catalysts were in situ prepared by the temperature-programmed reaction of moo(3) and carbon-supported mo precursors with nh(3). it is found that selectivity to the unsaturated alcohol is maximum for the mo(2)n/g sample, where crotylalcohol selectivities exceed the 60% during all time in reaction. higher selectivity surface sites are associated with the (200) planes of the gamma-mo(2)n crystallites. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | alpha,beta-unsaturated aldehydes ; catalysts ; selectivity ; cinnamaldehyde ; platinum ; carbides |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000077537200006 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138191]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Nacl Educ Distancia, Fac Ciencias, Dept Quim Inorgan, Madrid 28040, Spain 2.CSIC, Inst Catalisis & Petroleoquim, E-28049 Madrid, Spain 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Guerrero-Ruiz, A,Zhang, Y,Bachiller-Baeza, B,et al. Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides[J]. catalysis letters,1998,55(3-4):165-168. |
| APA | Guerrero-Ruiz, A,Zhang, Y,Bachiller-Baeza, B,&Rodriguez-Ramos, I.(1998).Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides.catalysis letters,55(3-4),165-168. |
| MLA | Guerrero-Ruiz, A,et al."Hydrogenation of crotonaldehyde over carbon-supported molybdenum nitrides".catalysis letters 55.3-4(1998):165-168. |
入库方式： OAI收割
来源：大连化学物理研究所
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