The v-v energy transfer of highly vibrationally excited states (I) - Vibrational quenching of CO(v) by CO2
文献类型：期刊论文
| 作者 | Wang, BS; Gu, YS; He, Y; Kong, FA |
| 刊名 | chinese science bulletin
 |
| 出版日期 | 1998-09-01 |
| 卷号 | 43期号:18页码:1536-1541 |
| 关键词 | time-resolved IR spectrum highly vibrational excited state vibrational energy transfer |
| 英文摘要 | the relaxation of the highly vibrationally excited co (v = 1-8) by co2 is studied by time-resolved fourier transform infrared emission spectroscopy (tr ftir). 193 nm laser photolysis of the mixture of chbr3 with o-2 generates the highly vibrationally excited co(v) molecules. tr ftir records the intense infrared emission of co(v-->v - i). the vibrational populations of each level of co(v) have been determined by the method of spectral simulation. based on the evolution of the time resolved populations and the differential method, 8 energy transfer rate constants of co (v = 1-8) to co2 molecules are obtained: (5.7 +/- 0.1), (5.9 +/- 0.1), (5.2 +/- 0.2), (3.4 +/- 0.2), (2.4 +/- 0.3), (2.2 +/- 0.4), (2.0 +/- 0.4) and (1.8 +/- 0.6) (10(-14) cm(3).molecule(-1).s(-1)), respectively. a two-channel energy transfer model can explain the feature of the quenching of co(v) by co2. for the lower vibrational states of co, the vibrational energy transfers preferentially to the upsilon(3) mode of co2. for the higher levels, the major quenching channel changes to the vibrational energy exchange between co(v-->v - 1) and the upsilon(1) mode of co2. |
| WOS标题词 | science & technology |
| 类目[WOS] | multidisciplinary sciences |
| 研究领域[WOS] | science & technology - other topics |
| 关键词[WOS] | rates ; n2o |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000076896600008 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138194]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Shandong Univ, Dept Chem, Jinan 250100, Peoples R China 2.Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, BS,Gu, YS,He, Y,et al. The v-v energy transfer of highly vibrationally excited states (I) - Vibrational quenching of CO(v) by CO2[J]. chinese science bulletin,1998,43(18):1536-1541. |
| APA | Wang, BS,Gu, YS,He, Y,&Kong, FA.(1998).The v-v energy transfer of highly vibrationally excited states (I) - Vibrational quenching of CO(v) by CO2.chinese science bulletin,43(18),1536-1541. |
| MLA | Wang, BS,et al."The v-v energy transfer of highly vibrationally excited states (I) - Vibrational quenching of CO(v) by CO2".chinese science bulletin 43.18(1998):1536-1541. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。