Homogeneous mono- and bimetallic palladium based catalysts for the carbonylation of allyl chloride
文献类型：期刊论文
| 作者 | Jiang, H; Xu, Y; Liao, SJ; Yu, DR; Chen, H; Li, XJ |
| 刊名 | journal of molecular catalysis a-chemical
 |
| 出版日期 | 1998-03-12 |
| 卷号 | 130期号:1-2页码:79-84 |
| 关键词 | carbonylation allyl chloride homogeneous bimetallic catalysts |
| 英文摘要 | pdcl2(tppts)(2) [tppts = (m-c6h4so3na)(3)p] is used as catalyst in the carbonylation of allyl chloride. this catalyst exhibits very high activity and selectivity in the dilute alcoholic-aqueous naoh/toluene medium under atmospheric pressure of carbon monoxide at 40 degrees c, ethanol plays an important role for increasing the catalytic activity and selectivity of pdcl2(tppts)(2). the turnover reaches 2.7 x 10(4) (mol co/mol pd) in 21.5 h when the mole ratio of substrate/catalyst is 3 x 10(4). a synergic effect was observed when a second transition metal compound was added to the catalytic system. (c) 1998 elsevier science b.v. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | atmospheric-pressure carbonylation ; multimetallic catalysts ; ruthenium catalysts ; sodium-hydroxide ; complexes ; halides ; hydroformylation ; hydrogenation ; behavior ; iodides |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000073456800008 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138195]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Sichuan Univ, Dept Chem, Chengdu 610064, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, H,Xu, Y,Liao, SJ,et al. Homogeneous mono- and bimetallic palladium based catalysts for the carbonylation of allyl chloride[J]. journal of molecular catalysis a-chemical,1998,130(1-2):79-84. |
| APA | Jiang, H,Xu, Y,Liao, SJ,Yu, DR,Chen, H,&Li, XJ.(1998).Homogeneous mono- and bimetallic palladium based catalysts for the carbonylation of allyl chloride.journal of molecular catalysis a-chemical,130(1-2),79-84. |
| MLA | Jiang, H,et al."Homogeneous mono- and bimetallic palladium based catalysts for the carbonylation of allyl chloride".journal of molecular catalysis a-chemical 130.1-2(1998):79-84. |
入库方式： OAI收割
来源：大连化学物理研究所
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