Properties and applications of mixed packing capillary electrochromatography
文献类型：期刊论文
| 作者 | Zhang, LH; Zhang, YK; Shi, W; Zou, HF |
| 刊名 | hrc-journal of high resolution chromatography
 |
| 出版日期 | 1999-12-01 |
| 卷号 | 22期号:12页码:666-670 |
| 关键词 | capillary electrochromatography mixed packing technique electroosmotic flow retention mechanism fast analysis |
| 英文摘要 | mixed packing capillary electrochromatography (mp cec) with the stationary phase comprising a physical mixture of strong cation exchange (scx) phase and octadecpilyl (ods) phase was developed. with the existence of a sulfonic acid group on the surface of scx, not only could the electroosmotic flow (eof) remain high at low ph, but also the hydrophilicity of the stationary phase was increased greatly, leading to broad adaptable ranges of both ph and organic modifier concentration in the mobile phase. at the same time, with the coexistence of c-18 on the surface of ods, both the retention and the resolution of samples vr ere improved. accordingly, mp cec combined the advantages of both scs and ods columns. effects of operation parameters on eof and the capacity factors of solutes as well as the retention mechanism of such a column were studied systematically. in addition, mp cec columns were used in the analysis of strong polar solutes as well as for the high speed separation of acidic, basic, and neutral compounds in a single fun. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | liquid-chromatography ; stationary-phase ; separation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000084494100003 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138209]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Natl Chromatog R&A Ctr, Dalian 116011, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, LH,Zhang, YK,Shi, W,et al. Properties and applications of mixed packing capillary electrochromatography[J]. hrc-journal of high resolution chromatography,1999,22(12):666-670. |
| APA | Zhang, LH,Zhang, YK,Shi, W,&Zou, HF.(1999).Properties and applications of mixed packing capillary electrochromatography.hrc-journal of high resolution chromatography,22(12),666-670. |
| MLA | Zhang, LH,et al."Properties and applications of mixed packing capillary electrochromatography".hrc-journal of high resolution chromatography 22.12(1999):666-670. |
入库方式： OAI收割
来源：大连化学物理研究所
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