OH spillover from a gamma-Al2O3 support in the partial oxidation of methane over Ru/Al2O3
文献类型:期刊论文
作者 | Wang, DZ; Li, ZL; Luo, CR; Weng, WZ; Wan, HL |
刊名 | chemical engineering science
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出版日期 | 2003-02-01 |
卷号 | 58期号:3-6页码:887-893 |
关键词 | kinetics modelling multiphase reactions selectivity methane oxidation spillover |
英文摘要 | the microkinetics of the oxidation of methane on ru/al2o3 is developed using a tap reactor. the shapes of the response curves of reactants and products are used to identify the elementary reactions and their rate parameters. the support, which strongly adsorbs h2o, participates in the reaction sequence through its supply of hydroxyl to metal particles by spillover, and this step is of kinetic significance. the relative rates of the elementary reactions that give overall partial oxidation or total oxidation are discussed. (c) 2003 elsevier science ltd. all rights reserved. |
WOS标题词 | science & technology ; technology |
类目[WOS] | engineering, chemical |
研究领域[WOS] | engineering |
关键词[WOS] | synthesis gas ; catalysts ; tap ; system |
收录类别 | ISTP ; SCI |
语种 | 英语 |
WOS记录号 | WOS:000181575600045 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/138216] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Tsing Hua Univ, Dept Chem Engn, Beijing 100084, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, DZ,Li, ZL,Luo, CR,et al. OH spillover from a gamma-Al2O3 support in the partial oxidation of methane over Ru/Al2O3[J]. chemical engineering science,2003,58(3-6):887-893. |
APA | Wang, DZ,Li, ZL,Luo, CR,Weng, WZ,&Wan, HL.(2003).OH spillover from a gamma-Al2O3 support in the partial oxidation of methane over Ru/Al2O3.chemical engineering science,58(3-6),887-893. |
MLA | Wang, DZ,et al."OH spillover from a gamma-Al2O3 support in the partial oxidation of methane over Ru/Al2O3".chemical engineering science 58.3-6(2003):887-893. |
入库方式: OAI收割
来源:大连化学物理研究所
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