A microcalorimetric device for measurement of differential heat of adsorption on surface of solid catalysts
文献类型：期刊论文
| 作者 | Li, L; Wang, XD; Shen, JY; Zhou, LX; Zhang, T |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2003-11-01 |
| 卷号 | 24期号:11页码:872-876 |
| 关键词 | hydrogen gas/solid adsorption system differential heat of adsorption microcalorimeter error analysis |
| 英文摘要 | a microcalorimetric device for the measurement of differential heat of adsorption on the surface of solid catalysts is described. in the device, a setaram heat flow microcalorimeter is used to measure the heat evolved from the sample. at the same time, an mks baratron capacitance manometer connected to a high vacuum system is employed to measure the amount of gas adsorbed on the sample. besides, a special all-metal vessel for the measurement of differential heat of adsorption on highly active catalysts, which can be operated under the conditions of high vacuum and wide temperature range, was designed and constructed. the microcalorimeter was calibrated with standard materials. the measurement of differential heat of adsorption such as h-2 on pt/sio2 and gamma-mo2n was carried out. the pt/sio2 sample was prepared by impregnation of silica with acetic solution of h2ptcl6.6h(2)o and the gamma-mo2n sample was prepared by temperature-programmed reductive nitriding of highly pure moo3 in a flow of pure nh3. the experimental results for the adsorption heat are in good agreement with those published in the literature. the error analysis of the experimental data shows that the relative errors for the measurement of adsorption heat are within 4%. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | molybdenum nitride ; supported platinum ; h-2 ; co |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000187322500016 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138238]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Nanjing Univ, Dept Chem, Nanjing 210093, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, L,Wang, XD,Shen, JY,et al. A microcalorimetric device for measurement of differential heat of adsorption on surface of solid catalysts[J]. chinese journal of catalysis,2003,24(11):872-876. |
| APA | Li, L,Wang, XD,Shen, JY,Zhou, LX,&Zhang, T.(2003).A microcalorimetric device for measurement of differential heat of adsorption on surface of solid catalysts.chinese journal of catalysis,24(11),872-876. |
| MLA | Li, L,et al."A microcalorimetric device for measurement of differential heat of adsorption on surface of solid catalysts".chinese journal of catalysis 24.11(2003):872-876. |
入库方式： OAI收割
来源：大连化学物理研究所
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