Effect of Pd on catalytic performance of Zr-Mn-K catalyst for CO hydrogenation to methanol and isobutanol
文献类型：期刊论文
| 作者 | He, DP; Ding, YJ; Yin, HM; Zhu, HJ; Xiong, JM; Luo, HY |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2003-09-01 |
| 卷号 | 24期号:9页码:658-662 |
| 关键词 | palladium zirconium manganese potassium carbon monoxide hydrogenation methanol isobutanol |
| 英文摘要 | the influence of pd on the catalytic performance of zr-mn-k catalyst for the selective synthesis of methanol and isobutanol from syngas was investigated. compared with zr-mn-k catalyst, the pd-promoted zr-mn-k catalyst significantly improved the reaction activity. under the reaction conditions of sv = 10000 h(-1), p = 8.0 mpa and t = 673 k, the space time yield of alcohols increased greatly from 122.8 to 232.6 g/(kg-h) when 1.5% pd (pd(no3)(2) as precursor) was addedd into the zr-mn-k catalyst, and the selectivity for isobutanol increased from 15.5% to 21.7%. however, the catalytic activity and selectivity for isobutanol greatly decreased when the pd loading exceeded 1.5%. the influence of the reaction conditions was also investigated. the reaction conditions of 15000 h(-1), higher pressure and 673 k are optimum for isobutanol synthesis from co hydrogenation. the chemisorption of h-2 and co on zr-mn-k and pd/zr-mn-k catalysts revealed that h-2 and co uptakes on pd/zr-mn-k catalyst are higher than those on zr-mn-k catalyst. the higher h-2 and co uptakes on pd/zr-mn-k catalyst would be in favor of enhancement in the rate of methanol and isobutanol synthesis. the uptakes of h-2 and co decreased with pd loading in excess of 1.5%, so that the space time yield of methanol and isobutanol decreased. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | syngas |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000185982100006 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138303]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, DP,Ding, YJ,Yin, HM,et al. Effect of Pd on catalytic performance of Zr-Mn-K catalyst for CO hydrogenation to methanol and isobutanol[J]. chinese journal of catalysis,2003,24(9):658-662. |
| APA | He, DP,Ding, YJ,Yin, HM,Zhu, HJ,Xiong, JM,&Luo, HY.(2003).Effect of Pd on catalytic performance of Zr-Mn-K catalyst for CO hydrogenation to methanol and isobutanol.chinese journal of catalysis,24(9),658-662. |
| MLA | He, DP,et al."Effect of Pd on catalytic performance of Zr-Mn-K catalyst for CO hydrogenation to methanol and isobutanol".chinese journal of catalysis 24.9(2003):658-662. |
入库方式： OAI收割
来源：大连化学物理研究所
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