A solution-reaction isoperibol calorimeter and standard molar enthalpies of formation of Ln(hq)(2)Ac (Ln = La, Pr)
文献类型：期刊论文
| 作者 | Yu, HG; Liu, Y; Tan, ZC; Dong, JX; Zou, TJ; Huang, XM; Qu, SS |
| 刊名 | thermochimica acta
 |
| 出版日期 | 2003-05-19 |
| 卷号 | 401期号:2页码:217-224 |
| 关键词 | solution-reaction isoperibol calorimeter enthalpy of solution standard molar enthalpy of formation coordination compound of rare earth 8-hydroxyquinoline acetic acid |
| 英文摘要 | an on-line solution-reaction isoperibol calorimeter has been constructed. the performance of the apparatus was evaluated by measuring the molar enthalpy of solution of kcl in water at 298.15 k. the uncertainty and the inaccurary of the experimental results were within +/-0.3% compared with the recommended reference data. using the calorimeter, the molar enthalpies of reaction for the following two reactions: lacl(3)(.)7h(2)o(s)+2hhq(s)+naac(s) = la(hq)(2)ac(s)+nacl(s)+2hcl(g)+7h(2)o(l) and prcl(3)(.)6h(2)o(s)+2hhq(s)+naac(s) = pr(hq)(2)ac(s)+nacl(s)+2hcl(g)+6h(2)o(l), were determined at t = 298.15 k, as -(78.3 +/- 0.6) and -(97.3 +/- 0.5)kj mol(-1), respectively. from the above molar enthalpies of reaction and other auxiliary thermodynamic quantities, the standard molar enthalpies of formation of la(hq)2ac and pr(hq)2ac, at t = 298.15 k, have been derived to be -(1535.5 +/- 0.7) and -(1536.7 +/- 0.6) kj mol(-1), respectively. (c) 2002 elsevier science b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000183007300015 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138310]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Wuhan Univ, Dept Chem, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, HG,Liu, Y,Tan, ZC,et al. A solution-reaction isoperibol calorimeter and standard molar enthalpies of formation of Ln(hq)(2)Ac (Ln = La, Pr)[J]. thermochimica acta,2003,401(2):217-224. |
| APA | Yu, HG.,Liu, Y.,Tan, ZC.,Dong, JX.,Zou, TJ.,...&Qu, SS.(2003).A solution-reaction isoperibol calorimeter and standard molar enthalpies of formation of Ln(hq)(2)Ac (Ln = La, Pr).thermochimica acta,401(2),217-224. |
| MLA | Yu, HG,et al."A solution-reaction isoperibol calorimeter and standard molar enthalpies of formation of Ln(hq)(2)Ac (Ln = La, Pr)".thermochimica acta 401.2(2003):217-224. |
入库方式： OAI收割
来源：大连化学物理研究所
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