Preparation of Ru metal nanoparticles in mesoporous materials: influence of sulfur on the hydrogenating activity
文献类型：期刊论文
| 作者 | Tian, P; Blanchard, J; Fajerwerg, K; Breysse, M; Vrinat, M; Liu, ZM |
| 刊名 | microporous and mesoporous materials
 |
| 出版日期 | 2003-06-19 |
| 卷号 | 60期号:1-3页码:197-206 |
| 关键词 | hydrogenation mesoporous materials ruthenium tetralin benzene acidity |
| 英文摘要 | hydrogenating catalysts were prepared by inserting ru into the pores of mesoporous al-mcm-41 materials by selective adsorption of [ru(nh3)(6)](3+). ru/support catalysts were obtained after reduction with h-2. the activities of these catalysts in hydrogenation reactions were compared to those of ru/hy and ru/sio2. the catalytic properties in the absence of sulfur were tested in benzene hydrogenation, and the intrinsic activities of all the catalysts (either supported on mesoporous materials or on zeolites) were identical. it was concluded from this result that the dispersion of the ru metallic phase was similar for all these catalysts. these samples were tested in the tetralin hydrogenation in pure h-2 and in the presence of h2s (330 ppm of h2s in h-2). they were found to be much less active than the zeolite-supported catalysts in the presence of h2s. it is proposed that the lower activity of the catalysts supported on mesoporous materials is either due to their milder acidity, as evidenced by nh3-tpd, cumene cracking and pyridine desorption experiments, or to the localization of the ru nanoparticles on alumina islands. (c) 2003 elsevier science inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
| 关键词[WOS] | ruthenium sulfide clusters ; aromatic-hydrocarbons ; molecular-sieves ; catalysts ; zeolites ; improvement ; adsorption ; benzene ; acidity ; mcm-41 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000183748700018 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138314]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Paris 06, Lab React Surface, UMR CNRS, F-75252 Paris 05, France 2.Inst Rech Catalyse, CNRS, UPR, F-69626 Villeurbanne, France 3.Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tian, P,Blanchard, J,Fajerwerg, K,et al. Preparation of Ru metal nanoparticles in mesoporous materials: influence of sulfur on the hydrogenating activity[J]. microporous and mesoporous materials,2003,60(1-3):197-206. |
| APA | Tian, P,Blanchard, J,Fajerwerg, K,Breysse, M,Vrinat, M,&Liu, ZM.(2003).Preparation of Ru metal nanoparticles in mesoporous materials: influence of sulfur on the hydrogenating activity.microporous and mesoporous materials,60(1-3),197-206. |
| MLA | Tian, P,et al."Preparation of Ru metal nanoparticles in mesoporous materials: influence of sulfur on the hydrogenating activity".microporous and mesoporous materials 60.1-3(2003):197-206. |
入库方式： OAI收割
来源：大连化学物理研究所
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