Dimerization of propylene by bis(beta-ketiminate) nickel(II) and cobalt(II) catalysts in the presence of organoaluminum activator and phosphine ligand
文献类型：期刊论文
| 作者 | Wu, SZ; Lu, SW |
| 刊名 | applied catalysis a-general
 |
| 出版日期 | 2003-06-30 |
| 卷号 | 246期号:2页码:295-301 |
| 关键词 | bis(p-ketiminate) nickel(II) and cobalt(II) complexes dimerization of propylene Al co-catalyst phosphine ligand |
| 英文摘要 | a preliminary study of the catalytic behavior of bis(beta-ketiminate) nickel(ii) and cobalt(ii) complexes in the dimerization of propylene was undertaken in combination with organoaluminum co-catalyst and ancillary phosphine ligand. the effects of type and relative amounts of aluminum co-catalyst as well as the nature of nickel and cobalt precatalysts were investigated. the results showed that the presence of ancillary phosphine ligand deeply modified the activity and selectivity of catalytic system, especially at the reaction temperature below 0 degreesc. an extremely high turnover frequency up to 268,000 h(-1) and a rather hi-h selectivity to dimers (95.6%) by the bis(n-(2,6-dimethylphenyl)-4-aminopent-3-en-2-ono) nickel(ii) complex (1c) in the presence of et3al2cl3 and pcy3 was achieved in the propylene dimerization under appropriate reaction conditions. (c) 2003 elsevier science b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; life sciences & biomedicine |
| 类目[WOS] | chemistry, physical ; environmental sciences |
| 研究领域[WOS] | chemistry ; environmental sciences & ecology |
| 关键词[WOS] | ziegler-type catalysts ; complexes ; 2,3-dimethylbutenes ; oligomerization ; cocatalysts ; ethylene ; chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000184026400010 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138315]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Res Ctr Catalysis, Dalian 116011, Liaoning, Peoples R China 2.Dalian Chem Phy Chem Co Ltd, Dalian 116011, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, SZ,Lu, SW. Dimerization of propylene by bis(beta-ketiminate) nickel(II) and cobalt(II) catalysts in the presence of organoaluminum activator and phosphine ligand[J]. applied catalysis a-general,2003,246(2):295-301. |
| APA | Wu, SZ,&Lu, SW.(2003).Dimerization of propylene by bis(beta-ketiminate) nickel(II) and cobalt(II) catalysts in the presence of organoaluminum activator and phosphine ligand.applied catalysis a-general,246(2),295-301. |
| MLA | Wu, SZ,et al."Dimerization of propylene by bis(beta-ketiminate) nickel(II) and cobalt(II) catalysts in the presence of organoaluminum activator and phosphine ligand".applied catalysis a-general 246.2(2003):295-301. |
入库方式： OAI收割
来源：大连化学物理研究所
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