中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Femtosecond spectroscopy study of electronically excited states of Chlorophyll a molecules in ethanol

文献类型:期刊论文

作者Shiu, YJ; Shi, Y; Hayashi, M; Su, C; Han, KL; Lin, SH
刊名chemical physics letters
出版日期2003-08-29
卷号378期号:1-2页码:202-210
英文摘要a femtosecond transient absorption technique is used to investigate the vibrational frequencies of the first electronically excited state of chlorophyll a. from the quantum beats analysis, we obtain vibrational frequencies within 98-791 cm(-1). based on these frequencies, we calculate the absorption and fluorescence spectra using the displaced-distorted harmonic potential surface model. the ratio of the absorption intensities of the first and second excited states yields similar to7.5. we perform various excitations to obtain anisotropy profiles and find that they vary between -0.005 +/- 0.005 and 0.41 +/- 0.015. to understand the kinetics appearing in the profiles, we propose a microscopic model. (c) 2003 elsevier b.v. all rights reserved.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical ; physics, atomic, molecular & chemical
研究领域[WOS]chemistry ; physics
关键词[WOS]transient absorption ; dynamics ; spectra ; allophycocyanin ; monomers ; raman
收录类别SCI
语种英语
WOS记录号WOS:000185124600033
公开日期2015-11-10
源URL[http://159.226.238.44/handle/321008/138358]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Acad Sinica, Inst Atom & Mol Sci, Taipei 106, Taiwan
2.Chinese Acad Sci, Dalian Inst Chem Phys, Ctr Computat Chem, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
4.Natl Taiwan Univ, Ctr Condensed Matter Sci, Taipei 106, Taiwan
5.Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan
推荐引用方式
GB/T 7714
Shiu, YJ,Shi, Y,Hayashi, M,et al. Femtosecond spectroscopy study of electronically excited states of Chlorophyll a molecules in ethanol[J]. chemical physics letters,2003,378(1-2):202-210.
APA Shiu, YJ,Shi, Y,Hayashi, M,Su, C,Han, KL,&Lin, SH.(2003).Femtosecond spectroscopy study of electronically excited states of Chlorophyll a molecules in ethanol.chemical physics letters,378(1-2),202-210.
MLA Shiu, YJ,et al."Femtosecond spectroscopy study of electronically excited states of Chlorophyll a molecules in ethanol".chemical physics letters 378.1-2(2003):202-210.

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来源:大连化学物理研究所

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