Reaction of CH radical with O-2 by time-resolved FTIR spectroscopy
文献类型：期刊论文
| 作者 | Ren, L; Kong, FN |
| 刊名 | chinese science bulletin
 |
| 出版日期 | 2003-06-01 |
| 卷号 | 48期号:12页码:1225-1229 |
| 关键词 | CH radical time-resolved Fourier transform IR emission CO CO2 |
| 英文摘要 | the reaction of ch radical with o-2 has been experimentally investigated by time-resolved fourier transform ir emission spectroscopy. ch radicals were generated by multi-photon uv laser photolysis of bromoform (chbr3) in gaseous phase. highly vibrationally excited product co (nu=1-12) with a near boltzmann distribution was observed after the reaction. the vibrational temperature of co is estimated as high as 14400 1400 k and the averaged vibrational energy is about 25.8 kcal.mol(-1). the emission intensity of co is not sensitive to the quenching gas, which indicates that there is no early barrier in the reaction of ch+o-2. however, the theoretically predicted product co2 has not been found in the experiment. |
| WOS标题词 | science & technology |
| 类目[WOS] | multidisciplinary sciences |
| 研究领域[WOS] | science & technology - other topics |
| 关键词[WOS] | rate constants ; no ; product ; o2 ; co |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000184249300015 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138394]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ren, L,Kong, FN. Reaction of CH radical with O-2 by time-resolved FTIR spectroscopy[J]. chinese science bulletin,2003,48(12):1225-1229. |
| APA | Ren, L,&Kong, FN.(2003).Reaction of CH radical with O-2 by time-resolved FTIR spectroscopy.chinese science bulletin,48(12),1225-1229. |
| MLA | Ren, L,et al."Reaction of CH radical with O-2 by time-resolved FTIR spectroscopy".chinese science bulletin 48.12(2003):1225-1229. |
入库方式： OAI收割
来源：大连化学物理研究所
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