中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Studies on electrochemical stability of room temperature ionic liquids

文献类型:期刊论文

作者Yang, JZ; Jin, Y; Cao, YH; Sun, LX; Tan, ZC
刊名chemical journal of chinese universities-chinese
出版日期2004-09-01
卷号25期号:9页码:1733-1735
关键词room temperature ionic liquid electrochemical stability BPBF4 BMIBF4 EMISE
英文摘要in this paper three air and water-stable room temperature ionic liquids (rtils): n-butylpyridinium tetrafluoroborate(bpbf4), 1-butyl-3-methylimidazolium tetrafluoroborate(bmibf4), and 1-ethyl-3-methylimidazolium ethyl sulfate(emise) were synthesized. their electrochemical windows were measured by cyclic voltammetry at 303. 15-343. 15 k. the cyclic voltammograms show the order of windows which represent the electrochemical stability of rtil is: bpbf4bmi+ \ - 0.95 v \ >bp+ \0.02 v \. it is very interesting that while the oxidative limit of anion bf4- and the reductive limit of all the cations reduce with the increase of temperature, but the oxidative limit of anion se- increases.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, multidisciplinary
研究领域[WOS]chemistry
关键词[WOS]thermodynamics
收录类别SCI
语种英语
WOS记录号WOS:000224014600037
公开日期2015-11-10
源URL[http://159.226.238.44/handle/321008/138405]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Yang, JZ,Jin, Y,Cao, YH,et al. Studies on electrochemical stability of room temperature ionic liquids[J]. chemical journal of chinese universities-chinese,2004,25(9):1733-1735.
APA Yang, JZ,Jin, Y,Cao, YH,Sun, LX,&Tan, ZC.(2004).Studies on electrochemical stability of room temperature ionic liquids.chemical journal of chinese universities-chinese,25(9),1733-1735.
MLA Yang, JZ,et al."Studies on electrochemical stability of room temperature ionic liquids".chemical journal of chinese universities-chinese 25.9(2004):1733-1735.

入库方式: OAI收割

来源:大连化学物理研究所

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