Effect of composition of mobile phase on electrophoresis osmotic flow in monolithic capillary columns with low electroosmotic flow
文献类型：期刊论文
| 作者 | Zhang, LY; Zhang, WB; Zhang, YK |
| 刊名 | chinese journal of analytical chemistry
 |
| 出版日期 | 2004-05-01 |
| 卷号 | 32期号:5页码:569-572 |
| 关键词 | in situ polymerization monolithic capillary columns with low electroosmotic flow organic solvent electroosmotic flow |
| 英文摘要 | monolithic columns with low electroosmotic flow (eof) in the electric field have been prepared by in situ polymerization of butyl methacrylate and ethylene dimethacrylate in the presence of suitable porogenic solvents. parameters that might affect eof, such as the species and proportion of organic solvent, have been studied systematically. in the ph range of 2.3 similar to 9.8, steady eof could be obtatined with in 19.6 x 10(-10) m(2)v(-1) s(-1). when the proportion of organic solvent increased from 60% to 90%, the eof increased from 6.6 x 10(-10) m(2)v(-1)s(-1) to 48. 9 x 10(-10) m(2)v(-1) s(-1). the results show that this kind of monolithic column could keep low eof in the mode of cec. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | porous polymer monoliths ; stationary phases ; separation media ; liquid-chromatography ; electrochromatography ; performance |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000221785200004 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138406]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Natl Chromatog Res & Anal Ctr, Dalian 116011, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, LY,Zhang, WB,Zhang, YK. Effect of composition of mobile phase on electrophoresis osmotic flow in monolithic capillary columns with low electroosmotic flow[J]. chinese journal of analytical chemistry,2004,32(5):569-572. |
| APA | Zhang, LY,Zhang, WB,&Zhang, YK.(2004).Effect of composition of mobile phase on electrophoresis osmotic flow in monolithic capillary columns with low electroosmotic flow.chinese journal of analytical chemistry,32(5),569-572. |
| MLA | Zhang, LY,et al."Effect of composition of mobile phase on electrophoresis osmotic flow in monolithic capillary columns with low electroosmotic flow".chinese journal of analytical chemistry 32.5(2004):569-572. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。