The reuse of acidic ionic liquids as catalysts in diphenyl oxide alkylation with dodecene
文献类型：期刊论文
| 作者 | Piao, LY; Han, Y; Kou, Y |
| 刊名 | acta physico-chimica sinica
 |
| 出版日期 | 2004-09-01 |
| 卷号 | 20期号:9页码:1083-1088 |
| 关键词 | Lewis acidity ionic liquids diphenyl oxide dodecene alkylation reuse |
| 英文摘要 | the diphenyl oxide alkylation with dodecene catalyzed by acidic ionic liquids has been studied. the reuse potential of acidic ionic liquids has been investigated. the reasons for the deactivation of the acidic ionic liquids are the decomposition and leaching of the actual catalytic species al2cl7- from the interaction between acidic ionic liquids and diphenyl oxide. the interaction between acidic ionic liquids and diphenyl oxide couldn't be avoided by changing the cations of ionic liquids. the reuse problem of acidic ionic liquids can be solved when certain amount of alcl3 is added into the used ionic liquids. the yield of target product is still around 90% after 8 cycles of the ionic liquids. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | friedel-crafts acetylation ; clean technology ; solvents ; benzene ; ferrocene ; acylation ; media ; fecl3 ; alcl3 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000224034000005 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138436]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Peking Univ, Inst Chem Phys, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Piao, LY,Han, Y,Kou, Y. The reuse of acidic ionic liquids as catalysts in diphenyl oxide alkylation with dodecene[J]. acta physico-chimica sinica,2004,20(9):1083-1088. |
| APA | Piao, LY,Han, Y,&Kou, Y.(2004).The reuse of acidic ionic liquids as catalysts in diphenyl oxide alkylation with dodecene.acta physico-chimica sinica,20(9),1083-1088. |
| MLA | Piao, LY,et al."The reuse of acidic ionic liquids as catalysts in diphenyl oxide alkylation with dodecene".acta physico-chimica sinica 20.9(2004):1083-1088. |
入库方式： OAI收割
来源：大连化学物理研究所
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