Oxidation of p-cresol to p-hydroxybenzaldehyde with molecular oxygen in the presence of CuMn-oxide heterogeneous catalyst
文献类型:期刊论文
作者 | Wang, F; Yang, GY; Zhang, W; Wu, WH; Xu, J |
刊名 | advanced synthesis & catalysis
![]() |
出版日期 | 2004-05-01 |
卷号 | 346期号:6页码:633-638 |
关键词 | copper p-cresol heterogeneous catalysis p-hydroxybenzaldehyde manganese |
英文摘要 | a high-yield synthesis of p-hydroxybenzaldehyde from p-cresol and molecular oxygen was achieved over a cumn-oxide supported carbon catalyst. the reaction parameters such as pressure, stirring speed, reaction temperature, solvent, and the amount of sodium hydroxide in the reaction media were optimized. as a result, a high conversion of p-cresol (99%) and a high selectivity to p-hydroxybenzaldehyde (96%) were realized at the same time. catalyst separation and recycling tests clearly showed that the reaction proceeded on the heterogeneous catalyst but not on dissolved species. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, applied ; chemistry, organic |
研究领域[WOS] | chemistry |
关键词[WOS] | liquid-phase oxidation ; reimer-tiemann reaction ; saturated-hydrocarbons ; one-step ; air ; activation ; complexes ; phenols ; copper ; sieves |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000222129300008 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/138447] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, F,Yang, GY,Zhang, W,et al. Oxidation of p-cresol to p-hydroxybenzaldehyde with molecular oxygen in the presence of CuMn-oxide heterogeneous catalyst[J]. advanced synthesis & catalysis,2004,346(6):633-638. |
APA | Wang, F,Yang, GY,Zhang, W,Wu, WH,&Xu, J.(2004).Oxidation of p-cresol to p-hydroxybenzaldehyde with molecular oxygen in the presence of CuMn-oxide heterogeneous catalyst.advanced synthesis & catalysis,346(6),633-638. |
MLA | Wang, F,et al."Oxidation of p-cresol to p-hydroxybenzaldehyde with molecular oxygen in the presence of CuMn-oxide heterogeneous catalyst".advanced synthesis & catalysis 346.6(2004):633-638. |
入库方式: OAI收割
来源:大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。