Application of SPE composite microelectrodes to the study of the spillover of adsorbed species on electrode surfaces
文献类型：期刊论文
| 作者 | Jiang, JH; Wu, BL; Cha, CS; Zhai, RS |
| 刊名 | journal of electroanalytical chemistry
 |
| 出版日期 | 1998-03-31 |
| 卷号 | 445期号:1-2页码:13-16 |
| 关键词 | solid polymer electrolyte spillover surface diffusion composite microelectrode adsorbed hydrogen |
| 英文摘要 | the electrochemical behavior of ferrocene in acetonitrile at the platinum\nafion (r) interface was investigated using spe composite microelectrodes. two parallel reactions take place at the interface. the redox reaction of ferrocene\ferricinium ions predominates at the platinum\nafion (r) composite microdisk electrode, while the adsorption or desorption of atomic hydrogen predominates at the platinum black\nafion (r) composite powder microelectrode. this fact implies that the electrochemical reactions take place only at the interface and the adsorption of atomic hydrogen can occur on surface sites remote from the interface. the spe composite microelectrode seems to be a potential technique of investigating the spillover of adsorbed species on the electrode surface. (c) 1998 elsevier science s.a. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; electrochemistry |
| 研究领域[WOS] | chemistry ; electrochemistry |
| 关键词[WOS] | organic electrochemistry ; nafion interface ; reduction ; electrocatalysis ; oxidation ; stability ; catalysis ; kinetics ; cell |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000073249600003 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138495]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, JH,Wu, BL,Cha, CS,et al. Application of SPE composite microelectrodes to the study of the spillover of adsorbed species on electrode surfaces[J]. journal of electroanalytical chemistry,1998,445(1-2):13-16. |
| APA | Jiang, JH,Wu, BL,Cha, CS,&Zhai, RS.(1998).Application of SPE composite microelectrodes to the study of the spillover of adsorbed species on electrode surfaces.journal of electroanalytical chemistry,445(1-2),13-16. |
| MLA | Jiang, JH,et al."Application of SPE composite microelectrodes to the study of the spillover of adsorbed species on electrode surfaces".journal of electroanalytical chemistry 445.1-2(1998):13-16. |
入库方式： OAI收割
来源：大连化学物理研究所
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