Synergic effect of polymer-supported bimetallic catalysts in the hydrogenation and isomerization of 1-octene
文献类型：期刊论文
| 作者 | Liu, CQ; Xu, Y; Liao, SJ; Yu, DR |
| 刊名 | journal of molecular catalysis a-chemical
 |
| 出版日期 | 1999-12-15 |
| 卷号 | 149期号:1-2页码:119-123 |
| 关键词 | polymer-supported bimetallic catalyst synergic effect 1-octene hydrogenation isomerization |
| 英文摘要 | the catalytic properties of the bimetallic catalysts for the hydrogenation and isomerization of 1-octene were investigated. the pvp-pdcl2-1/2co(oac)(2) bimetallic catalyst reduced by nabh4 exhibited a remarkable bimetallic synergic effect under mild conditions of 40 degrees c and 0.1 mpa. the maximum turnover frequency (tofmax, mol h-2/mol pd min) can be nearly doubled compared with that of the reaction catalyzed by the monometallic catalyst, and simultaneously the isomerization:of 1-octene to 2-octene and 3-octene was inhibited significantly. (c) 1999 elsevier science b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | homogeneous multimetallic catalysts ; selective hydrogenation ; palladium-ruthenium ; butadiene ; clusters ; gas |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000084148900012 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138537]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, CQ,Xu, Y,Liao, SJ,et al. Synergic effect of polymer-supported bimetallic catalysts in the hydrogenation and isomerization of 1-octene[J]. journal of molecular catalysis a-chemical,1999,149(1-2):119-123. |
| APA | Liu, CQ,Xu, Y,Liao, SJ,&Yu, DR.(1999).Synergic effect of polymer-supported bimetallic catalysts in the hydrogenation and isomerization of 1-octene.journal of molecular catalysis a-chemical,149(1-2),119-123. |
| MLA | Liu, CQ,et al."Synergic effect of polymer-supported bimetallic catalysts in the hydrogenation and isomerization of 1-octene".journal of molecular catalysis a-chemical 149.1-2(1999):119-123. |
入库方式： OAI收割
来源：大连化学物理研究所
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