Rotational state-to-state energy transfer of NH2((A)over-tilde(2)A(1)) in beam-gas condition
文献类型：期刊论文
| 作者 | Dong, F; Li, XC; Zhang, M; Wang, XY; Lou, NQ |
| 刊名 | journal of chemical physics
 |
| 出版日期 | 1999-12-15 |
| 卷号 | 111期号:23页码:10578-10586 |
| 英文摘要 | the detailed study on the rotational state-to-state energy transfer (rset) of nh2((a) over tilde (2)a(1)) at a relative translational energy of about 360 cm(-1) has been reported herein, by combining self-breakdown pulsed dc discharge and a photon counting technique. the transferred populations from the parent levels to the daughter levels have been obtained through the spectral simulations. it is clear that the rotational state distributions depend not only on the rotational quantum numbers of the initial and collisionally populated states, but also on the quantum number ka. it is interesting to find that the probability of rset behaves differently depending on the rotational quantum numbers of the parent levels, i.e., the exponential angular momentum transfer law (amt) is preferred with the relatively low rotational levels, while the exponential energy gap law is preferred with the relatively high levels. according to the sudden approximation and the theory of osborne , the experimental results are explained qualitatively. (c) 1999 american institute of physics. [s0021-9606(99)00247-0]. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | integral cross-sections ; angular-momentum model ; inelastic-scattering ; molecular-collisions ; quantum scattering ; propensity rules ; rates ; oh |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000083927200024 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138541]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dong, F,Li, XC,Zhang, M,et al. Rotational state-to-state energy transfer of NH2((A)over-tilde(2)A(1)) in beam-gas condition[J]. journal of chemical physics,1999,111(23):10578-10586. |
| APA | Dong, F,Li, XC,Zhang, M,Wang, XY,&Lou, NQ.(1999).Rotational state-to-state energy transfer of NH2((A)over-tilde(2)A(1)) in beam-gas condition.journal of chemical physics,111(23),10578-10586. |
| MLA | Dong, F,et al."Rotational state-to-state energy transfer of NH2((A)over-tilde(2)A(1)) in beam-gas condition".journal of chemical physics 111.23(1999):10578-10586. |
入库方式： OAI收割
来源：大连化学物理研究所
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