UV photolysis of oxalyl chloride and 2,3-butanedione studied by time-resolved FTIR
文献类型：期刊论文
| 作者 | Li, Q; Li, HZ; Kong, F |
| 刊名 | acta physico-chimica sinica
 |
| 出版日期 | 1999-03-01 |
| 卷号 | 15期号:3页码:259-264 |
| 关键词 | oxalyl chloride 2 UV photolysis IR emission spectrum 3-butanedione |
| 英文摘要 | the photodissociation of oxalyl chloride anti 2,3-butanedione at 193nm and 248nm have been studied by time-resolved ftir emission spectroscopy, the ir fluorescence emission was observed and the rotational and vibrational populations ai the co product were obtained. it is suggested that the photolysis mechanism is two rco radicals formed via a fission of c-c bond, followed by a decomposition of the rco intermediate to vibrationally excited co(v) and r radical. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | vibrational-state distributions ; emission-spectroscopy ; 193 nm ; rotational-state ; acetone ; photodissociation ; dynamics |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000079433200012 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138544]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Q,Li, HZ,Kong, F. UV photolysis of oxalyl chloride and 2,3-butanedione studied by time-resolved FTIR[J]. acta physico-chimica sinica,1999,15(3):259-264. |
| APA | Li, Q,Li, HZ,&Kong, F.(1999).UV photolysis of oxalyl chloride and 2,3-butanedione studied by time-resolved FTIR.acta physico-chimica sinica,15(3),259-264. |
| MLA | Li, Q,et al."UV photolysis of oxalyl chloride and 2,3-butanedione studied by time-resolved FTIR".acta physico-chimica sinica 15.3(1999):259-264. |
入库方式： OAI收割
来源：大连化学物理研究所
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