Studies on the preparation of bimetallic RhCo3(CO)(12)/SiO2 catalysts by infrared spectroscopy
文献类型：期刊论文
| 作者 | Huang, L; Xu, YD |
| 刊名 | progress in natural science
 |
| 出版日期 | 1999-09-01 |
| 卷号 | 9期号:9页码:662-671 |
| 关键词 | [Rh(CO)(2)Cl](2) Co-2(CO)(8) RhCo3(CO)(12) silica hydroformylation |
| 英文摘要 | the preparation of bimetallic rh-co catalysts with rh loading of 1 %, rh and co atomic ratio of 1:3 from [rh(co)(2)cl](2) and cobalt carbonyls (co-2(co)(8) and/or co-4(co)(12)) on the surface of sio2 has been investigated by means of in situ ir spectroscopy. the bimetallic rhco3 cluster can be efficiently formed from ([rh(co)(2)cl](2) + co-4(co)(12))/sio2 by thermal treatment under a reducing atmosphere. in particular, (rh+ + co2+)/sio2 derived from [rh(co)(2)cl](2) and co-4(co)(12) likewise can be efficiently transformed to the rhco3 cluster under the ethylene hydroformylation atmosphere at 423 k. |
| WOS标题词 | science & technology ; technology |
| 类目[WOS] | materials science, multidisciplinary ; multidisciplinary sciences |
| 研究领域[WOS] | materials science ; science & technology - other topics |
| 关键词[WOS] | hydroformylation ; carbonyls |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000082523300004 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138629]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, L,Xu, YD. Studies on the preparation of bimetallic RhCo3(CO)(12)/SiO2 catalysts by infrared spectroscopy[J]. progress in natural science,1999,9(9):662-671. |
| APA | Huang, L,&Xu, YD.(1999).Studies on the preparation of bimetallic RhCo3(CO)(12)/SiO2 catalysts by infrared spectroscopy.progress in natural science,9(9),662-671. |
| MLA | Huang, L,et al."Studies on the preparation of bimetallic RhCo3(CO)(12)/SiO2 catalysts by infrared spectroscopy".progress in natural science 9.9(1999):662-671. |
入库方式： OAI收割
来源：大连化学物理研究所
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