Partial oxidation of methane and ethane to synthesis gas over a LiLaNiO/gamma-Al2O3 catalyst
文献类型：期刊论文
| 作者 | Liu, SL; Xiong, GX; Sheng, SS; Yang, WS |
| 刊名 | applied catalysis a-general
 |
| 出版日期 | 2000-05-15 |
| 卷号 | 198期号:1-2页码:261-266 |
| 关键词 | partial oxidation of methane and ethane synthesis gas LiLaNiO/gamma-Al2O3 catalyst crystal phase structure carbon deposition sintering and loss of nickel |
| 英文摘要 | partial oxidation of methane and ethane to synthesis gas over a lilanio/gamma-al2o3 catalyst was investigated with a flow reactor, aas, xps, and xrd. excellent reaction performance for ch4-c2h6-o-2 to synthesis gas over the lilanio/gamma-al(2)q(3) is achieved at 1073 k, obtaining co selectivity of 90-95% and ch4 conversion of similar to 97%, with a wide range of c2h6 content in the feed and of space velocity. meanwhile, 100, 200 and 500 h life tests of the lilanio/gamma-al2o3 for natural gas-o-2 to synthesis gas were also performed. the results indicate that the lilanio/gamma-al2o3 catalyst not only possesses excellent reaction performance (ch4 conversion similar to 95%, co selectivity similar to 98%), good carbon deposition resistance, but also has a relatively stable element component and a stable crystal phase structure during a 500h life test experiment under conditions of 1123 k, natural gas/o-2 ratio of 1.90 and space velocity of 2.7 x 10(5) 1/(kg h). (c) 2000 elsevier science b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; life sciences & biomedicine |
| 类目[WOS] | chemistry, physical ; environmental sciences |
| 研究领域[WOS] | chemistry ; environmental sciences & ecology |
| 关键词[WOS] | selective oxidation ; low-temperature ; syngas ; monoliths ; alkali ; oxide ; co |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000086809600023 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138662]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, SL,Xiong, GX,Sheng, SS,et al. Partial oxidation of methane and ethane to synthesis gas over a LiLaNiO/gamma-Al2O3 catalyst[J]. applied catalysis a-general,2000,198(1-2):261-266. |
| APA | Liu, SL,Xiong, GX,Sheng, SS,&Yang, WS.(2000).Partial oxidation of methane and ethane to synthesis gas over a LiLaNiO/gamma-Al2O3 catalyst.applied catalysis a-general,198(1-2),261-266. |
| MLA | Liu, SL,et al."Partial oxidation of methane and ethane to synthesis gas over a LiLaNiO/gamma-Al2O3 catalyst".applied catalysis a-general 198.1-2(2000):261-266. |
入库方式： OAI收割
来源：大连化学物理研究所
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