The mechanism of asymmetric reduction catalyzed by a C-2 symmetric bis-amino alcohol catalyst - In situ NMR study of the structure of new type of dual-centered catalyst
文献类型：期刊论文
| 作者 | Zhao, JK; Han, XW; Liu, XM; Bao, XH; Hang, JF; Jiang, B |
| 刊名 | science in china series b-chemistry
 |
| 出版日期 | 2000-02-01 |
| 卷号 | 43期号:1页码:40-50 |
| 关键词 | 2D gradient experiment in situ NMR diaminodihydroxylborane bis-oxazaborolidine |
| 英文摘要 | by means of h-1,c-13, b-11 nmr, polar transfer dept135, dept90 and 2d nmr experiments, ir, etc, the structure of the diaminodihydroxyl ligand and its derivatives used in the asymmetric reduction of prochiral ketones were detected. the catalysts derived from the ligand and borane formed in situ were also studied and the structure transformations in solution were monitored. the structure of the catalyst was proved to be a new type of dual-centered catalyst-bisoxazaborolidine. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000085514600006 |
| 公开日期 | 2015-11-10 |
| 源URL | [http://159.226.238.44/handle/321008/138671]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, JK,Han, XW,Liu, XM,et al. The mechanism of asymmetric reduction catalyzed by a C-2 symmetric bis-amino alcohol catalyst - In situ NMR study of the structure of new type of dual-centered catalyst[J]. science in china series b-chemistry,2000,43(1):40-50. |
| APA | Zhao, JK,Han, XW,Liu, XM,Bao, XH,Hang, JF,&Jiang, B.(2000).The mechanism of asymmetric reduction catalyzed by a C-2 symmetric bis-amino alcohol catalyst - In situ NMR study of the structure of new type of dual-centered catalyst.science in china series b-chemistry,43(1),40-50. |
| MLA | Zhao, JK,et al."The mechanism of asymmetric reduction catalyzed by a C-2 symmetric bis-amino alcohol catalyst - In situ NMR study of the structure of new type of dual-centered catalyst".science in china series b-chemistry 43.1(2000):40-50. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。