中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Mixed-conducting perovskite-type SrxBi1-xFeO3_delta oxygen-permeating membranes

文献类型:期刊论文

作者Shao, ZP; Cong, Y; Xiong, GX; Sheng, SS; Yang, WS
刊名science in china series b-chemistry
出版日期2000-08-01
卷号43期号:4页码:421-427
关键词oxygen membrane SrxBi1-xFeO3-delta crystal structure phase stability permeation flux
英文摘要srxbi1-xfeo3-delta (sbf) series mixed conductors were synthesized using standard ceramic method. the properties of such materials were characterized by xrd, o-2-tpd techniques. abnormal crystal phenomena were found and explained and correlated with the oxygen permeation results. by analysis of the critical radius (r(c)), the degree of openness of the lattice (f-v) and the average metal-oxygen bonding energy of the perovskite lattice (abe), it was proposed that the oxygen permeation flux is determined mainly by the oxygen diffusion rate in bulk when 1-x less than or equal to 0.5, and by the concentration of oxygen vacancy when 1-x greater than or equal to 0.5. the stability of sr0.5bi0.5feo3-delta was also investigated, and the high stability of it was attributed to the stable bo6 octahedra.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, multidisciplinary
研究领域[WOS]chemistry
关键词[WOS]solid electrolytes ; partial oxidation ; fuel-cells ; reactors ; methane
收录类别SCI
语种英语
WOS记录号WOS:000089289400010
公开日期2015-11-10
源URL[http://159.226.238.44/handle/321008/138691]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Shao, ZP,Cong, Y,Xiong, GX,et al. Mixed-conducting perovskite-type SrxBi1-xFeO3_delta oxygen-permeating membranes[J]. science in china series b-chemistry,2000,43(4):421-427.
APA Shao, ZP,Cong, Y,Xiong, GX,Sheng, SS,&Yang, WS.(2000).Mixed-conducting perovskite-type SrxBi1-xFeO3_delta oxygen-permeating membranes.science in china series b-chemistry,43(4),421-427.
MLA Shao, ZP,et al."Mixed-conducting perovskite-type SrxBi1-xFeO3_delta oxygen-permeating membranes".science in china series b-chemistry 43.4(2000):421-427.

入库方式: OAI收割

来源:大连化学物理研究所

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