Mixed-conducting perovskite-type SrxBi1-xFeO3_delta oxygen-permeating membranes
文献类型:期刊论文
作者 | Shao, ZP; Cong, Y; Xiong, GX; Sheng, SS; Yang, WS |
刊名 | science in china series b-chemistry
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出版日期 | 2000-08-01 |
卷号 | 43期号:4页码:421-427 |
关键词 | oxygen membrane SrxBi1-xFeO3-delta crystal structure phase stability permeation flux |
英文摘要 | srxbi1-xfeo3-delta (sbf) series mixed conductors were synthesized using standard ceramic method. the properties of such materials were characterized by xrd, o-2-tpd techniques. abnormal crystal phenomena were found and explained and correlated with the oxygen permeation results. by analysis of the critical radius (r(c)), the degree of openness of the lattice (f-v) and the average metal-oxygen bonding energy of the perovskite lattice (abe), it was proposed that the oxygen permeation flux is determined mainly by the oxygen diffusion rate in bulk when 1-x less than or equal to 0.5, and by the concentration of oxygen vacancy when 1-x greater than or equal to 0.5. the stability of sr0.5bi0.5feo3-delta was also investigated, and the high stability of it was attributed to the stable bo6 octahedra. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, multidisciplinary |
研究领域[WOS] | chemistry |
关键词[WOS] | solid electrolytes ; partial oxidation ; fuel-cells ; reactors ; methane |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000089289400010 |
公开日期 | 2015-11-10 |
源URL | [http://159.226.238.44/handle/321008/138691] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Shao, ZP,Cong, Y,Xiong, GX,et al. Mixed-conducting perovskite-type SrxBi1-xFeO3_delta oxygen-permeating membranes[J]. science in china series b-chemistry,2000,43(4):421-427. |
APA | Shao, ZP,Cong, Y,Xiong, GX,Sheng, SS,&Yang, WS.(2000).Mixed-conducting perovskite-type SrxBi1-xFeO3_delta oxygen-permeating membranes.science in china series b-chemistry,43(4),421-427. |
MLA | Shao, ZP,et al."Mixed-conducting perovskite-type SrxBi1-xFeO3_delta oxygen-permeating membranes".science in china series b-chemistry 43.4(2000):421-427. |
入库方式: OAI收割
来源:大连化学物理研究所
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